4-Bromomethylbenzoic acid

ChemicalBook > CAS DataBase List > 4-Bromomethylbenzoic acid

4-Bromomethylbenzoic acid

Product Name: 4-Bromomethylbenzoic acid
CAS No.: 6232-88-8
Chemical Name: 4-Bromomethylbenzoic acid
Synonyms: 4-(BROMOMETHYL)BENZOIC ACID;ALPHA-BROMO-P-TOLUIC ACID;4-Bromomethylbenzoic;ALPHA-BROMO-P-TOLUYLIC ACID;AKOS BBS-00006715;Eprosartan USP RC D;RARECHEM AL BO 0068;A-BROMO-P-TOLUIC ACID;á-Bromo-p-toluic acid;à-bromo-p-toluic acid
CBNumber: CB6317157
Molecular Formula: C8H7BrO2
Formula Weight: 215.04
MOL File: 6232-88-8.mol

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4-Bromomethylbenzoic acid Property

Melting point:: 224-229 °C(lit.)
Boiling point:: 252.95°C (rough estimate)
Density: 1.5313 (rough estimate)
refractive index: 1.5500 (estimate)
storage temp.: Store below +30°C.
form: Crystalline Powder
pka: 4.10±0.10(Predicted)
color: White to beige
Water Solubility: Soluble in water.
BRN: 1862870
InChIKey: CQQSQBRPAJSTFB-UHFFFAOYSA-N
CAS DataBase Reference: 6232-88-8(CAS DataBase Reference)
EPA Substance Registry System: Benzoic acid, 4-(bromomethyl)- (6232-88-8)

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Safety

Hazard Codes: Xi,C
Risk Statements: 36/37/38
Safety Statements: 26-36
RIDADR: 3261
WGK Germany: 3
F: 19-21
Hazard Note: Irritant
TSCA: Yes
HazardClass: 8
PackingGroup: III
HS Code: 29163900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H314Causes severe skin burns and eye damage

H315Causes skin irritation

H318Causes serious eye damage

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P309IF exposed or if you feel unwell:

P310Immediately call a POISON CENTER or doctor/physician.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 159549
Product name: 4-(Bromomethyl)benzoic acid
Purity: 97%
Packaging: 5g
Price: $51.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 1238251
Product name: Eprosartan Related Compound D
Purity: United States Pharmacopeia (USP) Reference Standard
Packaging: 15mg
Price: $511
Updated: 2024/03/01

TCI Chemical

Product number: B0845
Product name: 4-(Bromomethyl)benzoic Acid
Purity: >97.0%(GC)(T)
Packaging: 5g
Price: $24
Updated: 2024/03/01

TCI Chemical

Product number: B0845
Product name: 4-(Bromomethyl)benzoic Acid
Purity: >97.0%(GC)(T)
Packaging: 25g
Price: $66
Updated: 2024/03/01

Alfa Aesar

Product number: L03371
Product name: 4-(Bromomethyl)benzoic acid, 97%
Packaging: 5g
Price: $38.65
Updated: 2024/03/01

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4-Bromomethylbenzoic acid Chemical Properties,Usage,Production

Chemical Properties

white to beige crystalline powder

Uses

4-(Bromomethyl)benzoic Acid is an intermediate in the synthesis of Eprosartan (E590100), a prototype of the imidazoleacrylic acid angiotensin II receptor antagonists used as an antihypertensive agent.

Uses

4-(Bromomethyl)benzoic acid acts as an intermediate in the synthesis of eprosartan, which is used as an antihypertensive agent. Further, it is used in the preparation of 5,10,15,20-tetra(m-hydroxyphenyl)chlorin (temoporfin), which is a second generation photosensitizer. In addition to this, it is used in the preparation of 4-(5-arylidene-2,4-dioxothiazolidin-3-yl) methylbenzoic acids.

Uses

4-(Bromomethyl)benzoic acid was used in the chemical modification of 5,10,15,20-tetra(m-hydroxyphenyl)chlorin (temoporfin), second generation photosensitizer. It was also used in the synthesis of 4-(5-arylidene-2,4-dioxothiazolidin-3-yl) methylbenzoic acids.

Purification Methods

Crystallise the acid from pKEst Me2CO. [Beilstein 9 IV 1745.]

4-Bromomethylbenzoic acid Preparation Products And Raw materials

Raw materials

P-XYLENE Cobalt naphthenate p-Toluic acid p-Cymene

Preparation Products

4-BROMOMETHYL BENZOYL CHLORIDE Fenpyroximate 4-(Aminomethyl)benzoic acid

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View Lastest Price from 4-Bromomethylbenzoic acid manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: 4-Bromomethylbenzoic acid 6232-88-8
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-12

Hebei Mojin Biotechnology Co., Ltd

Product: 4-Bromomethylbenzoic acid 6232-88-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-07-27

Zhuozhou Wenxi import and Export Co., Ltd

Product: 4-Bromomethylbenzoic acid 6232-88-8
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

6232-88-8, 4-Bromomethylbenzoic acidRelated Search:

Folic acid α-Lipoic Acid p-Toluic acid Citric acid 4-(Chloromethyl)benzoic acid 3-Methyl-2-nitrobenzoic acid Methyl 3-(bromomethyl)benzoate 3-(Trifluoromethyl)benzoic acid Methyl 4-(bromomethyl)benzoate 4-Bromobenzoic acid m-Toluic acid 4-(Aminomethyl)benzoic acid o-Toluic acid Methyl 2-bromobenzoate Ethyl 2-(Chlorosulfonyl)acetate 3-Methyl-4-nitrobenzoic acid IMatinib DiPiperidine IMpurity Ascoric Acid

ALPHA-BROMO-P-TOLUYLIC ACID

ALPHA-BROMO-P-TOLUIC ACID

AKOS BBS-00006715

A-BROMO-P-TOLUIC ACID

alpha-BroMo-p-toluic acid, 97% 50GR

Eprosartan USP RC D

Eprosartan related coMpound D

4-(BroMoMethyl)benzoic Acid, 95+%

p-Toluic acid, .alpha.-bromo-

p-Toluic acid, alpha-bromo-

4-(Bromomethyl)benzoic acid≥ 98% (HPLC)

á-Bromo-p-toluic acid

Eprosartan Impurity 4(Eprosartan USP RC D)

Eprosartan USP Related Compound D

Benzoidacid,4-(bromomethyl)-

Alpha-Bromo-P-Toluic Acid , 4-Bromomethylbenzoic Acid

4-(bromomethyl)-benzoicaci

4-CARBOXYBENZYL BROMIDE

4-(BROMOMETHYL)BENZOIC ACID

P-(BROMOMETHYL)BENZOIC ACID

P-CARBOXYBENZYL BROMIDE

RARECHEM AL BO 0068

alpha-bromo-para-toluic acid

alpha-bromotoluic acid

Benzoic acid, 4-(bromomethyl)-

à-bromo-p-toluic acid

α-bromo-p-toluic acid

alpha-Bromo-p-toluic acid,97%

4-(Bromomethyl)benzoic acid,α-Bromo-p-toluic acid

4-Bromomethylbenzoic

alpha-BroMo-p-toluic acid, 97% 10GR

4-(Bromomethyl)benzoic Acid &gt

Eprosartan Related Compound D (4-(bromomethyl)benzoic acid) (1238251)

α-Bromo-p-toluic acid

6232-88-8

6232-88-6

62832-88-8

C8H6BrO2

BrCH2C6H4CO2H

Organic Building Blocks

Carboxylic Acids

Carbonyl Compounds

Building Blocks

Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts

Organic acids

Acids and Derivatives

Halides

Aromatics