ChemicalBook > CAS DataBase List > 2-Chloro-6-methoxy-3-nitropyridine

2-Chloro-6-methoxy-3-nitropyridine

Product Name
2-Chloro-6-methoxy-3-nitropyridine
CAS No.
38533-61-8
Chemical Name
2-Chloro-6-methoxy-3-nitropyridine
Synonyms
oro-6-methoxy-3-nitropyridine;2-Chlor-6-methoxy-3-nitropyridin;2-CHLORO-3-NITRO-METHOXYPYRIDINE;2-Choro-3-nitro-6-methoxypyridine;2-CHLORO-6-METHOXY-3-NITROPYRIDINE;2-CHLORO-3-NITRO-6-METHOXYPYRIDINE;2-chloro-3-aMino-6-Methoxypyridine;Pyridine, 2-chloro-6-methoxy-3-nitro-;2-Chloro-6-methoxy-3-nitropyridine >2-Chloro-6-methoxy-3-nitropyridine 97%
CBNumber
CB6329477
Molecular Formula
C6H5ClN2O3
Formula Weight
188.57
MOL File
38533-61-8.mol
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2-Chloro-6-methoxy-3-nitropyridine Property

Melting point:
78-80 °C (lit.)
Boiling point:
298.5±35.0 °C(Predicted)
Density 
1.445±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Powder
pka
-2.34±0.10(Predicted)
color 
Off-white to yellow
Water Solubility 
Slightly soluble in water.
InChI
InChI=1S/C6H5ClN2O3/c1-12-5-3-2-4(9(10)11)6(7)8-5/h2-3H,1H3
InChIKey
DVRGUTNVDGIKTP-UHFFFAOYSA-N
SMILES
C1(Cl)=NC(OC)=CC=C1[N+]([O-])=O
CAS DataBase Reference
38533-61-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-44-20/21/22
Safety Statements 
26-37/39-36/37/39
WGK Germany 
3
Hazard Note 
Irritant
HazardClass 
6.1
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
C49909
Product name
2-Chloro-6-methoxy-3-nitropyridine
Purity
98%
Packaging
10g
Price
$79.6
Updated
2024/03/01
TCI Chemical
Product number
C1636
Product name
2-Chloro-6-methoxy-3-nitropyridine
Purity
>98.0%(GC)
Packaging
5g
Price
$45
Updated
2024/03/01
TCI Chemical
Product number
C1636
Product name
2-Chloro-6-methoxy-3-nitropyridine
Purity
>98.0%(GC)
Packaging
25g
Price
$145
Updated
2024/03/01
Alfa Aesar
Product number
H64076
Product name
2-Chloro-6-methoxy-3-nitropyridine, 98%
Packaging
25g
Price
$66.65
Updated
2024/03/01
Alfa Aesar
Product number
H64076
Product name
2-Chloro-6-methoxy-3-nitropyridine, 98%
Packaging
100g
Price
$223.65
Updated
2024/03/01
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2-Chloro-6-methoxy-3-nitropyridine Chemical Properties,Usage,Production

Chemical Properties

Light yellow Cryst

Uses

6-methoxy-3-nitropyridine-2-carbonitrile was synthesised from 2-Chloro-6-methoxy-3-nitropyridine. Reatant in the suzuki and negishi couplings reaction. Also as fine chemical intermediate.

Structure and conformation

2-chloro-6-methoxy-3-nitropyridine ( 2, 6, 3-CMNP) has a planar structure of the Cs point group symmetry. The three Cartesian displacements of the 17 atoms provide 45 internal modes. All 45 fundamental vibrations are active in both IR and Raman. For an N-atomic molecule, 2N-3 of all vibration is in plane and N-3 is out of plane. Thus, for 2-chloro-6-methoxy-3-nitropyridine, 31 of all the 45 vibrations are n-plane and 14 are out-of-plane.
The compound 2, 6, 3-CMNP has only one methoxy group at the 6th position; therefore there will be only one O-CH3 stretching mode. In case of HF/6-31+G (d, p) this O-C stretching vibration is observed at 1041 cm-1 and by the DFT calculations observed at 1069 cm-1. Each CH3 or OCH3 group rise to three C-H valance oscillations (2800-3000 cm-1) and three C-H deformations as suggested by Bellamy.

References

[1] Sharma B, et al. Ab-initio Hartee-Fock and Density functional theory calculations of 2-Chloro-6-methoxy-3-nitropyridine. Arch. Appl. Sci. Res, 2011; 3: 334-344.

2-Chloro-6-methoxy-3-nitropyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Chloro-6-methoxy-3-nitropyridine Suppliers

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View Lastest Price from 2-Chloro-6-methoxy-3-nitropyridine manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
2-Chloro-6-methoxy-3-nitropyridine 38533-61-8
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-02
Henan Fengda Chemical Co., Ltd
Product
2-Chloro-6-methoxy-3-nitropyridine 38533-61-8
Price
US $5.00-0.10/KG
Min. Order
1KG
Purity
98%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-09
Career Henan Chemical Co
Product
2-Chloro-6-methoxy-3-nitropyridine 38533-61-8
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-22

38533-61-8, 2-Chloro-6-methoxy-3-nitropyridineRelated Search:

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  • 2-CHLORO-3-NITRO-6-METHOXYPYRIDINE
  • 2-CHLORO-6-METHOXY-3-NITROPYRIDINE
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  • 2-Chloro-6-methoxy-3-nitropyridine 97%
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  • 2-Chloro-6-methoxy-3-nitropyridine ISO 9001：2015 REACH
  • 38533-61-8
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  • C6H5CIN2O3
  • Chloropyridines
  • Halopyridines
  • Pyridines
  • Heterocyclic Building Blocks
  • Halogenated Heterocycles
  • Building Blocks
  • Heterocycle-Pyridine series
  • blocks
  • Pyridines
  • Pyridine
  • Chloropyridines
  • Halopyridines
  • Pyridine series
  • Halides
  • compounds of pyridine
  • C6Heterocyclic Building Blocks
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • alkyl chloride|nitro-compound
  • 1