2-Chloro-6-methoxy-3-nitropyridine
- Product Name
- 2-Chloro-6-methoxy-3-nitropyridine
- CAS No.
- 38533-61-8
- Chemical Name
- 2-Chloro-6-methoxy-3-nitropyridine
- Synonyms
- oro-6-methoxy-3-nitropyridine;2-Chlor-6-methoxy-3-nitropyridin;2-CHLORO-3-NITRO-METHOXYPYRIDINE;2-Choro-3-nitro-6-methoxypyridine;2-CHLORO-6-METHOXY-3-NITROPYRIDINE;2-CHLORO-3-NITRO-6-METHOXYPYRIDINE;2-chloro-3-aMino-6-Methoxypyridine;Pyridine, 2-chloro-6-methoxy-3-nitro-;2-Chloro-6-methoxy-3-nitropyridine >2-Chloro-6-methoxy-3-nitropyridine 97%
- CBNumber
- CB6329477
- Molecular Formula
- C6H5ClN2O3
- Formula Weight
- 188.57
- MOL File
- 38533-61-8.mol
2-Chloro-6-methoxy-3-nitropyridine Property
- Melting point:
- 78-80 °C (lit.)
- Boiling point:
- 298.5±35.0 °C(Predicted)
- Density
- 1.445±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- Powder
- pka
- -2.34±0.10(Predicted)
- color
- Off-white to yellow
- Water Solubility
- Slightly soluble in water.
- InChI
- InChI=1S/C6H5ClN2O3/c1-12-5-3-2-4(9(10)11)6(7)8-5/h2-3H,1H3
- InChIKey
- DVRGUTNVDGIKTP-UHFFFAOYSA-N
- SMILES
- C1(Cl)=NC(OC)=CC=C1[N+]([O-])=O
- CAS DataBase Reference
- 38533-61-8(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-44-20/21/22
- Safety Statements
- 26-37/39-36/37/39
- WGK Germany
- 3
- Hazard Note
- Irritant
- HazardClass
- 6.1
- HS Code
- 29333990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- C49909
- Product name
- 2-Chloro-6-methoxy-3-nitropyridine
- Purity
- 98%
- Packaging
- 10g
- Price
- $79.6
- Updated
- 2024/03/01
- Product number
- C1636
- Product name
- 2-Chloro-6-methoxy-3-nitropyridine
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $45
- Updated
- 2024/03/01
- Product number
- C1636
- Product name
- 2-Chloro-6-methoxy-3-nitropyridine
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $145
- Updated
- 2024/03/01
- Product number
- H64076
- Product name
- 2-Chloro-6-methoxy-3-nitropyridine, 98%
- Packaging
- 25g
- Price
- $66.65
- Updated
- 2024/03/01
- Product number
- H64076
- Product name
- 2-Chloro-6-methoxy-3-nitropyridine, 98%
- Packaging
- 100g
- Price
- $223.65
- Updated
- 2024/03/01
2-Chloro-6-methoxy-3-nitropyridine Chemical Properties,Usage,Production
Chemical Properties
Light yellow Cryst
Uses
6-methoxy-3-nitropyridine-2-carbonitrile was synthesised from 2-Chloro-6-methoxy-3-nitropyridine. Reatant in the suzuki and negishi couplings reaction. Also as fine chemical intermediate.
Structure and conformation
2-chloro-6-methoxy-3-nitropyridine ( 2, 6, 3-CMNP) has a planar structure of the Cs point group symmetry. The three Cartesian displacements of the 17 atoms provide 45 internal modes. All 45 fundamental vibrations are active in both IR and Raman. For an N-atomic molecule, 2N-3 of all vibration is in plane and N-3 is out of plane. Thus, for 2-chloro-6-methoxy-3-nitropyridine, 31 of all the 45 vibrations are n-plane and 14 are out-of-plane.
The compound 2, 6, 3-CMNP has only one methoxy group at the 6th position; therefore there will be only one O-CH3 stretching mode. In case of HF/6-31+G (d, p) this O-C stretching vibration is observed at 1041 cm-1 and by the DFT calculations observed at 1069 cm-1. Each CH3 or OCH3 group rise to three C-H valance oscillations (2800-3000 cm-1) and three C-H deformations as suggested by Bellamy.
References
[1] Sharma B, et al. Ab-initio Hartee-Fock and Density functional theory calculations of 2-Chloro-6-methoxy-3-nitropyridine. Arch. Appl. Sci. Res, 2011; 3: 334-344.
2-Chloro-6-methoxy-3-nitropyridine Preparation Products And Raw materials
Raw materials
Preparation Products
2-Chloro-6-methoxy-3-nitropyridine Suppliers
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View Lastest Price from 2-Chloro-6-methoxy-3-nitropyridine manufacturers
- Product
- 2-Chloro-6-methoxy-3-nitropyridine 38533-61-8
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 ton
- Release date
- 2024-12-02
- Product
- 2-Chloro-6-methoxy-3-nitropyridine 38533-61-8
- Price
- US $5.00-0.10/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-09
- Product
- 2-Chloro-6-methoxy-3-nitropyridine 38533-61-8
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2018-12-22