2-Chloro-6-methoxy-3-nitropyridine

Product Name: 2-Chloro-6-methoxy-3-nitropyridine
CAS No.: 38533-61-8
Chemical Name: 2-Chloro-6-methoxy-3-nitropyridine
Synonyms: oro-6-methoxy-3-nitropyridine;2-Chlor-6-methoxy-3-nitropyridin;2-CHLORO-3-NITRO-METHOXYPYRIDINE;2-Choro-3-nitro-6-methoxypyridine;2-CHLORO-6-METHOXY-3-NITROPYRIDINE;2-CHLORO-3-NITRO-6-METHOXYPYRIDINE;2-chloro-3-aMino-6-Methoxypyridine;Pyridine, 2-chloro-6-methoxy-3-nitro-;2-Chloro-6-methoxy-3-nitropyridine >2-Chloro-6-methoxy-3-nitropyridine 97%
CBNumber: CB6329477
Molecular Formula: C6H5ClN2O3
Formula Weight: 188.57
MOL File: 38533-61-8.mol

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2-Chloro-6-methoxy-3-nitropyridine Property

Melting point:: 78-80 °C (lit.)
Boiling point:: 298.5±35.0 °C(Predicted)
Density: 1.445±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: Powder
pka: -2.34±0.10(Predicted)
color: Off-white to yellow
Water Solubility: Slightly soluble in water.
InChI: InChI=1S/C6H5ClN2O3/c1-12-5-3-2-4(9(10)11)6(7)8-5/h2-3H,1H3
InChIKey: DVRGUTNVDGIKTP-UHFFFAOYSA-N
SMILES: C1(Cl)=NC(OC)=CC=C1[N+]([O-])=O
CAS DataBase Reference: 38533-61-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-44-20/21/22
Safety Statements: 26-37/39-36/37/39
WGK Germany: 3
Hazard Note: Irritant
HazardClass: 6.1
HS Code: 29333990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: C49909
Product name: 2-Chloro-6-methoxy-3-nitropyridine
Purity: 98%
Packaging: 10g
Price: $79.6
Updated: 2024/03/01

TCI Chemical

Product number: C1636
Product name: 2-Chloro-6-methoxy-3-nitropyridine
Purity: >98.0%(GC)
Packaging: 5g
Price: $45
Updated: 2024/03/01

TCI Chemical

Product number: C1636
Product name: 2-Chloro-6-methoxy-3-nitropyridine
Purity: >98.0%(GC)
Packaging: 25g
Price: $145
Updated: 2024/03/01

Alfa Aesar

Product number: H64076
Product name: 2-Chloro-6-methoxy-3-nitropyridine, 98%
Packaging: 25g
Price: $66.65
Updated: 2024/03/01

Alfa Aesar

Product number: H64076
Product name: 2-Chloro-6-methoxy-3-nitropyridine, 98%
Packaging: 100g
Price: $223.65
Updated: 2024/03/01

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2-Chloro-6-methoxy-3-nitropyridine Chemical Properties,Usage,Production

Chemical Properties

Light yellow Cryst

Uses

6-methoxy-3-nitropyridine-2-carbonitrile was synthesised from 2-Chloro-6-methoxy-3-nitropyridine. Reatant in the suzuki and negishi couplings reaction. Also as fine chemical intermediate.

Structure and conformation

2-chloro-6-methoxy-3-nitropyridine ( 2, 6, 3-CMNP) has a planar structure of the Cs point group symmetry. The three Cartesian displacements of the 17 atoms provide 45 internal modes. All 45 fundamental vibrations are active in both IR and Raman. For an N-atomic molecule, 2N-3 of all vibration is in plane and N-3 is out of plane. Thus, for 2-chloro-6-methoxy-3-nitropyridine, 31 of all the 45 vibrations are n-plane and 14 are out-of-plane.
The compound 2, 6, 3-CMNP has only one methoxy group at the 6th position; therefore there will be only one O-CH3 stretching mode. In case of HF/6-31+G (d, p) this O-C stretching vibration is observed at 1041 cm-1 and by the DFT calculations observed at 1069 cm-1. Each CH3 or OCH3 group rise to three C-H valance oscillations (2800-3000 cm-1) and three C-H deformations as suggested by Bellamy.

References

[1] Sharma B, et al. Ab-initio Hartee-Fock and Density functional theory calculations of 2-Chloro-6-methoxy-3-nitropyridine. Arch. Appl. Sci. Res, 2011; 3: 334-344.

2-Chloro-6-methoxy-3-nitropyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Chloro-6-methoxy-3-nitropyridine Suppliers

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View Lastest Price from 2-Chloro-6-methoxy-3-nitropyridine manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd

Product: 2-Chloro-6-methoxy-3-nitropyridine 38533-61-8
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 ton
Release date: 2024-12-02

Henan Fengda Chemical Co., Ltd

Product: 2-Chloro-6-methoxy-3-nitropyridine 38533-61-8
Price: US $5.00-0.10/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-09

Career Henan Chemical Co

Product: 2-Chloro-6-methoxy-3-nitropyridine 38533-61-8
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: Customized
Release date: 2018-12-22

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2-Chloro-6-methoxy-3-nitropyridine ISO 9001：2015 REACH

38533-61-8

38553-61-8

C6H5CIN2O3

Chloropyridines

Halopyridines

Pyridines

Heterocyclic Building Blocks

Halogenated Heterocycles

Building Blocks

Heterocycle-Pyridine series

blocks

Pyridines

Pyridine

Chloropyridines

Halopyridines

Pyridine series

Halides

compounds of pyridine

C6Heterocyclic Building Blocks

Halogenated Heterocycles

Heterocyclic Building Blocks

alkyl chloride|nitro-compound

1