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Analytical Chemistry

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Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Structure:
Chemical Name:
1,3-bis[3-(4,5-dihydro-1H-imidazol-2-yl)phenyl]urea dihydrochloride
CAS:
5318-76-3
MF:
C19H22Cl2N6O
Structure:
Chemical Name:
5H-dibenzo[a,d]cycloheptene
CAS:
256-81-5
MF:
C15H12
Structure:
Chemical Name:
NAPHTHALENE-13C10
CAS:
219526-41-7
MF:
C10H8
Structure:
Chemical Name:
Potassium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate
CAS:
105560-52-9
MF:
C32H12BF24K
Structure:
Chemical Name:
SODIUM O-IODOHIPPURATE
CAS:
133-17-5
MF:
C9H7INNaO3
Structure:
Chemical Name:
2,2',3,4',5,6,6'-HEPTACHLOROBIPHENYL
CAS:
74487-85-7
MF:
C12H3Cl7
Structure:
Chemical Name:
DIBENZ[A,I]ACRIDINE
CAS:
226-92-6
MF:
C21H13N
Chemical Name:
DIETHYL[2-HYDROXYPROPYL]AMINOETHYL SEPHADEX
CAS:
83382-89-2
Structure:
Chemical Name:
METHYL RICINELAIDATE
CAS:
7706-01-6
MF:
C19H36O3
Structure:
Chemical Name:
METFORMIN-D6, HYDROCHLORIDE
CAS:
1185166-01-1
MF:
C4H6ClD6N5
Structure:
Chemical Name:
Calcipotriol Monohydrate
CAS:
147657-22-5
MF:
C27H42O4
Structure:
Chemical Name:
Endo-3-amine-9-methyl-9-azabicyclo[3,3,1]nonane
CAS:
107007-95-4
MF:
C17 H22 N4 O
Chemical Name:
APOLIPOPROTEIN A-I, HUMAN
CAS:
1426185-50-3
Structure:
Chemical Name:
3,3',4,5,5'-PENTACHLOROBIPHENYL
CAS:
39635-33-1
MF:
C12H5Cl5
Structure:
Chemical Name:
2,3,3',4,4',5,5',6-OCTACHLOROBIPHENYL
CAS:
74472-53-0
MF:
C12H2Cl8
Structure:
Chemical Name:
3,4',5-TRICHLOROBIPHENYL
CAS:
38444-88-1
MF:
C12H7Cl3
Structure:
Chemical Name:
CIS-MEVINPHOS
CAS:
338-45-4
MF:
C7H13O6P
Structure:
Chemical Name:
3,4,5-TRICHLOROBIPHENYL
CAS:
53555-66-1
MF:
C12H7Cl3
Structure:
Chemical Name:
PN 203-831
CAS:
116169-18-7
MF:
C19H19N3O5
Structure:
Chemical Name:
N-(KETOCAPROYL)-D,L-HOMOSERINE LACTONE
CAS:
76924-95-3
MF:
C10H15NO4
Structure:
Chemical Name:
SILTHIOFAM
CAS:
175217-20-6
MF:
C13H21NOSSi
Structure:
Chemical Name:
METAM-SODIUM DIHYDRATE
CAS:
6734-80-1
MF:
C2H10NNaO3S2
Structure:
Chemical Name:
DIBENZO(A,C)ACRIDINE
CAS:
215-62-3
MF:
C21H13N
Structure:
Chemical Name:
ATRATON-DESISOPROPYL
CAS:
30360-56-6
MF:
C6H11N5O
Structure:
Chemical Name:
BROMBUTEROL
CAS:
41937-02-4
MF:
C12H18Br2N2O
Structure:
Chemical Name:
Pramipexole Impurity 16
CAS:
104632-27-1
MF:
C10H18ClN3S
Structure:
Chemical Name:
ethyl 5-(forMylaMino)-1H-pyrazole-4-carboxylate
CAS:
31055-19-3
MF:
C7H9N3O3
Structure:
Chemical Name:
2,2'-Bis-(1-adaMantyl)-4,4'-diMethoxybiphenyl
CAS:
932033-57-3
MF:
C34H42O2
Structure:
Chemical Name:
Dibenzyl chloroMethyl phosphate
CAS:
258516-84-6
MF:
C15H16ClO4P
Structure:
Chemical Name:
Orlistat Related Compound D
CAS:
130793-27-0
MF:
C29H53NO5
Structure:
Chemical Name:
3,4,4',5-TETRACHLOROBIPHENYL
CAS:
70362-50-4
MF:
C12H6Cl4
Structure:
Chemical Name:
7-AMINONITRAZEPAM
CAS:
4928-02-3
MF:
C15H13N3O
Structure:
Chemical Name:
4-BROMO-2,5-DIMETHOXYPHENETHYLAMINE HCL
CAS:
56281-37-9
MF:
C10H15BrClNO2
Structure:
Chemical Name:
(+)-SANTOLINA ALCOHOL
CAS:
35671-15-9
MF:
C10H18O
Structure:
Chemical Name:
2,2',3,5,5'-PENTACHLOROBIPHENYL
CAS:
52663-61-3
MF:
C12H5Cl5
Structure:
Chemical Name:
2,2'3,6,6'-PENTACHLOROBIPHENYL
CAS:
73575-54-9
MF:
C12H5Cl5
Structure:
Chemical Name:
2,3,3',4,5,6-HEXACHLOROBIPHENYL
CAS:
41411-62-5
MF:
C12H4Cl6
Structure:
Chemical Name:
2,3,3',5-TETRACHLOROBIPHENYL
CAS:
70424-67-8
MF:
C12H6Cl4
Structure:
Chemical Name:
2,3,3',4,6-PENTACHLOROBIPHENYL
CAS:
74472-35-8
MF:
C12H5Cl5
Structure:
Chemical Name:
2,3,3',4-TETRACHLOROBIPHENYL
CAS:
74338-24-2
MF:
C12H6Cl4
Structure:
Chemical Name:
2-HYDROXYEICOSANOIC ACID
CAS:
16742-48-6
MF:
C20H40O3
Structure:
Chemical Name:
BIS(2,4,4-TRIMETHYLPENTYL)DITHIOPHOSPHINIC ACID
CAS:
107667-02-7
MF:
C16H35PS2
Structure:
Chemical Name:
PYRIDATE METABOLITE
CAS:
40020-01-7
MF:
C10H7ClN2O
Structure:
Chemical Name:
PENFLUORON
CAS:
35367-31-8
MF:
C15H9F5N2O2
Structure:
Chemical Name:
DESMETHYLDOXEPIN
CAS:
1225-56-5
MF:
C18H19NO
Structure:
Chemical Name:
CHLORPYRIFOS-METHYL-OXON
CAS:
5598-52-7
MF:
C7H7Cl3NO4P
Structure:
Chemical Name:
(+)-MENTHOFURAN
CAS:
17957-94-7
MF:
C10H14O
Structure:
Chemical Name:
CHLORDIAZEPOXIDE-D5
CAS:
65891-81-8
MF:
C16H14ClN3O
Structure:
Chemical Name:
METHYL 3,5-DIFORMYL-1-INDOLIZINECARBOXYLATE
CAS:
163556-04-5
MF:
C12H9NO4
Structure:
Chemical Name:
HYDROXYCITRIC ACID LACTONE, (-)-(P)
CAS:
27750-13-6
MF:
C6H6O7
Structure:
Chemical Name:
WITHANOLIDE A(P)
CAS:
32911-62-9
MF:
C28H38O6
Structure:
Chemical Name:
METHYL TRIBROMOACETATE, 99
CAS:
3222-05-7
MF:
C3H3Br3O2
Structure:
Chemical Name:
GLYBURIDE RELATED COMPOUND B (25 MG) (METHYL-[[4-[2-[(5-CHLORO-2-METHOXYBENZOYL)-AMINO]ETHYL]PHENYL]SULFONYL]CARBAMATE) (AS)
CAS:
21165-77-5
MF:
C18H19ClN2O6S
Chemical Name:
Chitosan Hydrochloride
CAS:
70694-72-3
Structure:
Chemical Name:
2-ENEVALPROIC ACID
CAS:
60218-41-9
MF:
C8H14O2
Structure:
Chemical Name:
ETOBENZANID
CAS:
79540-50-4
MF:
C16H15Cl2NO3
Structure:
Chemical Name:
HEPTAKIS(3-O-ACETYL-2 6-DI-O-METHYL)-
CAS:
131889-29-7
MF:
C70H112O42
Structure:
Chemical Name:
BETAMETHASONE VALERATE RELATED COMPOUND A (50 MG) (BETAMETHASONE 21-VALERATE) (AS)
CAS:
2240-28-0
MF:
C27H37FO6
Structure:
Chemical Name:
TIZANIDINE RELATED COMPOUND C (50 MG) (1-ACETYLIMIDAZOLIDINE-2-THIONE)
CAS:
5391-52-6
MF:
C5H8N2OS
Structure:
Chemical Name:
Dichlorophosphorus tetraphenylporphyrin chloride
CAS:
84896-72-0
MF:
C44H28Cl3N4P
Structure:
Chemical Name:
N-(7-NITRO-4-BENZOFURAZANYL)-D-PROLYL
CAS:
159717-69-8
MF:
C11H9ClN4O4
Structure:
Chemical Name:
BISPHENOL F DIGLYCIDYL ETHER
CAS:
2095-03-6
MF:
C19H20O4
Structure:
Chemical Name:
MESO-1,2-BIS(4-METHOXYPHENYL)ETHYLENEDIAMINE
CAS:
58520-45-9
MF:
C16H20N2O2
Structure:
Chemical Name:
2,3,5,6-TETRACHLOROANISOLE
CAS:
6936-40-9
MF:
C7H4Cl4O
Structure:
Chemical Name:
19-HYDROXY-8(17),13-LABDADIEN-16,15-OLIDE
CAS:
82209-74-3
MF:
C20H30O3
Structure:
Chemical Name:
HFPB
CAS:
120945-63-3
MF:
C56H42BF48NaO11
Structure:
Chemical Name:
6H-BENZO[CD]PYREN-6-ONE
CAS:
3074-00-8
MF:
C19H10O
Structure:
Chemical Name:
9(Z),11(E)-OCTADECADIENOIC ACID
CAS:
2540-56-9
MF:
C18H32O2
Structure:
Chemical Name:
FAMPROFAZONE
CAS:
22881-35-2
MF:
C24H31N3O
Structure:
Chemical Name:
LINALYL ANTHRANILATE
CAS:
7149-26-0
MF:
C17H23NO2
Structure:
Chemical Name:
6,6-DIBENZYL-14-CROWN-4
CAS:
106868-21-7
MF:
C24H32O4
Structure:
Chemical Name:
NEOSOLANIOL
CAS:
36519-25-2
MF:
C19H26O8
Structure:
Chemical Name:
2,2',3,4',6-PENTACHLOROBIPHENYL
CAS:
68194-05-8
MF:
C12H5Cl5
Structure:
Chemical Name:
4-CHLOROBENZYLIDENE PHTHALIDE
CAS:
20526-97-0
MF:
C15H9ClO2
Structure:
Chemical Name:
DI-N-PENTYL PHTHALATE-D4
CAS:
358730-89-9
MF:
C18H22D4O4
Structure:
Chemical Name:
2,2',4,4',6-PENTABROMODIPHENYL ETHER
CAS:
189084-64-8
MF:
C12H5Br5O
Chemical Name:
Litmus paper blue
Structure:
Chemical Name:
1,5-dihydro-4H-imidazo[4,5-d]-1,2,3-triazin-4-one
CAS:
4656-86-4
MF:
C4H3N5O
Structure:
Chemical Name:
3-amino-5-(aminosulphonyl)-4-phenoxybenzoic acid
CAS:
28328-54-3
MF:
C13H12N2O5S
Structure:
Chemical Name:
2,6-diamino-5-(beta-D-glucopyranosyloxy)-(1H)-pyrimidin-4-one
CAS:
152-93-2
MF:
C10H16N4O7
Chemical Name:
Phenolohthalein paper
Chemical Name:
Potassium iodide statch paper
Structure:
Chemical Name:
Thiacloprid-Amid, Pestanal
CAS:
676228-91-4
MF:
C10H11ClN4OS
Structure:
Chemical Name:
Flufenacet OA, Pestanal
CAS:
201668-31-7
MF:
C11H12FNO3
Chemical Name:
Specialindicatorpaper
Structure:
Chemical Name:
Tralopyril
CAS:
122454-29-9
MF:
C12H5BrClF3N2
Structure:
Chemical Name:
Flucycloxuron
CAS:
113036-88-7
MF:
C25H20ClF2N3O3
Structure:
Chemical Name:
METHYL MYRISTELAIDATE
CAS:
72025-18-4
MF:
C15H28O2
Structure:
Chemical Name:
BISPHENOL F BIS(2,3-DIHYDROXYPROPYL) ETHER
CAS:
72406-26-9
MF:
C19H24O6
Structure:
Chemical Name:
uttronin A
CAS:
39941-51-0
MF:
C50H82O22
Structure:
Chemical Name:
Bisphenol TMC
CAS:
129188-99-4
MF:
C21H26O2
Structure:
Chemical Name:
2-[2-METHYL-D3-3-(TRIFLUOROMETHYL)PHENYLAMINO]NICOTINIC ACID
CAS:
1015856-60-6
MF:
C14H8D3F3N2O2
Structure:
Chemical Name:
L-A-HYDROXYGLUTARIC ACID DISODIUM)
CAS:
63512-50-5
MF:
C5H9NaO5
Structure:
Chemical Name:
2,2',3,4,5,6,6'-HEPTACHLOROBIPHENYL
CAS:
74472-49-4
MF:
C12H3Cl7
Structure:
Chemical Name:
2,4,4',6-TETRACHLOROBIPHENYL
CAS:
32598-12-2
MF:
C12H6Cl4
Structure:
Chemical Name:
SUDAN IV-D6
CAS:
1014689-18-9
MF:
C24H20N4O
Structure:
Chemical Name:
3,3',4,5-TETRACHLOROBIPHENYL
CAS:
70362-49-1
MF:
C12H6Cl4
Structure:
Chemical Name:
(+/-)-11-NOR-9-CARBOXY-DELTA9-THC
CAS:
104874-50-2
MF:
C21H28O4
Structure:
Chemical Name:
cis-Glimepiride
CAS:
684286-46-2
MF:
C24H34N4O5S
Structure:
Chemical Name:
ent-Voriconazole
CAS:
137234-63-0
MF:
C16H14F3N5O