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(1S,2R)-2-Amino-1,2-diphenylethanol

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(1S,2R)-2-Amino-1,2-diphenylethanol Basic information

Product Name:
(1S,2R)-2-Amino-1,2-diphenylethanol
Synonyms:
  • (1S,2R)-(-)-2-AMINO-1,2-DIPHENYLETHANOL
  • (1S,2R)-(+)-2-AMINO-1,2-DIPHENYLETHANOL
  • (1S,2R)-2-AMINO-1,2-DIPHENYLETHANOL
  • (1S,2R)-(+)-DIPHENYL-2-AMINOETHANOL
  • (1S,2R)-2-Amino-1,2-diphenylethanol,98%
  • (1S,2R)-(+)-2-Amino-1,2-diphenylethanol ,98% [ee:99%]
  • (1R,2S)-1,2-Diphenyl-1-amino-2-hydroxyethane
  • (1S,2R)-2-Amino-1,2-
CAS:
23364-44-5
MF:
C14H15NO
MW:
213.28
EINECS:
628-513-0
Product Categories:
  • Organic Building Blocks
  • Chiral Compound
  • chiral
  • Benzene derivatives
  • Amino Alcohols
  • Chiral Building Blocks
  • Chiral reagent
  • Amino Alcohols (Chiral)
  • Chiral Building Blocks
  • for Resolution of Acids
  • Optical Resolution
  • Synthetic Organic Chemistry
  • Amino Alcohols & Deriv.
  • CHIRAL CHEMICALS
  • Chiral chemicals
Mol File:
23364-44-5.mol
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(1S,2R)-2-Amino-1,2-diphenylethanol Chemical Properties

Melting point:
142-144 °C(lit.)
alpha 
7 º (c=0.6, EtOH)
Boiling point:
374.3±37.0 °C(Predicted)
Density 
1.148±0.06 g/cm3(Predicted)
refractive index 
7 ° (C=0.6, EtOH)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
very faint turbidity in Methanol
pka
11.70±0.45(Predicted)
form 
Crystalline Powder
color 
White to beige
optical activity
[α]25/D +7.0°, c = 0.6 in ethanol
BRN 
1212828
InChIKey
GEJJWYZZKKKSEV-KGLIPLIRSA-N
CAS DataBase Reference
23364-44-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-36
WGK Germany 
3
9
HS Code 
29221990

MSDS

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(1S,2R)-2-Amino-1,2-diphenylethanol Usage And Synthesis

Reaction

  1. Ligand used to make chiral oxaborolidines for the enantioselective alkynylation of aldehydes
  2. Ligand used in organoindium reagents for asymmetric Barbier-type allylations
  3. Ligand used in organoindium reagents for asymmetric Barbier-type propargylations

Chemical Properties

white to light yellow crystal powde

Uses

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol can be used:

  • To prepare vanadium(V) Schiff base complexes, which are used as catalysts in the oxidation of sulfides and olefins.
  • To prepare chiral selectors, which are immobilized on aminated silica gel, applicable as chiral stationary phase in HPLC.
  • To immobilize on the frame of α-zirconium phosphate to yield layered zirconium phosphonates, which are used in the heterogeneous catalysis.
  • As a chiral auxiliary in the preparation of homopropargylic alcohols from aliphatic and aromatic aldehydes.

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