ChemicalBook > CAS DataBase List > Benzhydrylamine
Benzhydrylamine
- Product Name
- Benzhydrylamine
- CAS No.
- 91-00-9
- Chemical Name
- Benzhydrylamine
- Synonyms
- BENZHYDRYLAMINE;1,1-Diphenylmethanamine;NSC 49127;AURORA KA-7667;Benzyldrylamine;Benzhydralamine;benzohydrylamine;Benzylhydrylamine;a-Phenylbenzylamine;diphenylMethylaMino
- CBNumber
- CB7409604
- Molecular Formula
- C13H13N
- Formula Weight
- 183.25
- MOL File
- 91-00-9.mol
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Benzhydrylamine Property
- Melting point:
- 12 °C (lit.)
- Boiling point:
- 295 °C (lit.)
- Density
- 1.063 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.595(lit.)
- Flash point:
- >230 °F
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- solubility
- Chloroform, DMSO, Methanol
- pka
- 8.41±0.10(Predicted)
- form
- Liquid
- color
- Clear colorless to yellow
- Specific Gravity
- 1.063
- Water Solubility
- Miscible with chloroform, dimethylsulfoxide and methanol. Slightly miscible with water.
- Sensitive
- Air Sensitive
- Merck
- 14,1076
- BRN
- 776434
- CAS DataBase Reference
- 91-00-9(CAS DataBase Reference)
- NIST Chemistry Reference
- Aminodiphenylmethane(91-00-9)
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Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 22-36/37/38
- Safety Statements
- 26-36
- RIDADR
- 2810
- WGK Germany
- 3
- RTECS
- DA4407300
- F
- 9-23
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29214990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- A53605
- Product name
- Benzhydrylamine
- Purity
- 97%
- Packaging
- 5g
- Price
- $43
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- A53605
- Product name
- Benzhydrylamine
- Purity
- 97%
- Packaging
- 25g
- Price
- $43.8
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B0124
- Product name
- Benzhydrylamine
- Purity
- >97.0%(GC)(T)
- Packaging
- 25mL
- Price
- $37
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B0124
- Product name
- Benzhydrylamine
- Purity
- >97.0%(GC)(T)
- Packaging
- 100mL
- Price
- $104
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- B24303
- Product name
- Benzhydrylamine, 97%
- Packaging
- 25g
- Price
- $65.65
- Updated
- 2024/03/01
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Benzhydrylamine Chemical Properties,Usage,Production
Chemical Properties
Colorless liquid
Uses
Benzhydrylamine is fine-chemical intermediate used for chiral resolution. It acts as an active pharmaceutical ingredient intermediate. It is also employed as a building block for chemical synthesis. Further, it is used in the preparation of furan-2-carboxylic acid benzhydrylamide by reacting with furan-2-carbonyl chloride.
Synthesis Reference(s)
Tetrahedron Letters, 27, p. 3033, 1986 DOI: 10.1016/S0040-4039(00)84709-7
Synthesis
1) synthesis of diphenylketoxime
After benzophenone 10g, oxammonium hydrochloride 6g, 95% ethanol 20mL are put into reaction flask stirring and dissolving, gradation adds sodium hydrate solid 11g.Finish, reaction solution is heated to 88 DEG C of reaction 2h, then pours in dilute hydrochloric acid solution by reaction solution, occurs white solid, filter to obtain diphenylketoxime 10.7g, yield 99%.
2) synthesis of benzhydrylamine
Diphenylketoxime 0.25g, 95% ethanol 5mL are put into reaction flask, after solution change is clear, adds concentration into 5 × 10 7cFU/mL waxy Bacillus solution 50mL, constant temperature 30 DEG C (rotating speed 200r/min) oscillatory reaction in shaking table.TLC detect without raw material time, add appropriate diatomite in reaction solution and carry out centrifugation, get supernatant liquid acidifying, with dichloromethane extraction, aqueous layer basified and with dichloromethane extraction concentrate to obtain benzhydrylamine 9.0g, yield 91%.
Purification Methods
Crystallise the amine from H2O. The free base absorbs CO2 from the atmosphere; store it accordingly. The hydrochloride M 219.7 m 293-295o, crystallises from H2O. [Beilstein 12 H 1323, 12 IV 3282.]
Benzhydrylamine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Benzhydrylamine manufacturers
Hebei Chuanghai Biotechnology Co,.LTD
- Product
- Aminodiphenylmethane 91-00-9
- Price
- US $5.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-15
Hebei Kingfiner Technology Development Co.Ltd
- Product
- Benzhydrylamine 91-00-9
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 50000kg
- Release date
- 2024-06-18
Hebei Weibang Biotechnology Co., Ltd
- Product
- Aminodiphenylmethane 91-00-9
- Price
- US $10.00/pc
- Min. Order
- 1公斤
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2021-06-15
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