Esters Aromatic acids fatty acid Fatty alcohols Boric acid Cyanide / nitrile Aromatic ketones Aromatic aldehydes Halogenated aliphatic hydrocarbons aliphatic ketones Amide Ethers Aromatics Aromatic alcohol Phosphine ligand Phenols Thiol / thiol Silane Acyl halide Sulfonates / Sulfinates salts Cyanate ester / isocyanate Nitro compounds Imide Olefin (cyclic and acyclic) The polycyclic compound Hydrazine Amine salt (ammonium salt) Aliphatic aldehydes Bicyclic compound Oxime Tricyclic compound Alkanes Sulfonyl halide Phosphonate / phosphonate Phosphorus halide Alkyne Carboxylic anhydride Urea Phosphorus-containing compound Siloxane Azo, diazo compound Ionic Liquids Thiocyanate / isothiocyanate Borate Sulfonates / Sulfinates Selenium compounds Guanidine salt Borane Thiourea Thiolate tetrafluoroborate Thiol ester Polycyclic compound Crown ether Sulfone, sulfoxide compound Hydrazone Imide, amidine Polyamines Tosylate Epoxide Azide Hydroxylamine Cyclodextrin
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Organic reagents

Esters Aromatic acids fatty acid Fatty alcohols Boric acid Cyanide / nitrile Aromatic ketones Aromatic aldehydes Halogenated aliphatic hydrocarbons aliphatic ketones Amide Ethers Aromatics Aromatic alcohol Phosphine ligand Phenols Thiol / thiol Silane Acyl halide Sulfonates / Sulfinates salts Cyanate ester / isocyanate Nitro compounds Imide Olefin (cyclic and acyclic) The polycyclic compound Hydrazine Amine salt (ammonium salt) Aliphatic aldehydes Bicyclic compound Oxime Tricyclic compound Alkanes Sulfonyl halide Phosphonate / phosphonate Phosphorus halide Alkyne Carboxylic anhydride Urea Phosphorus-containing compound Siloxane Azo, diazo compound Ionic Liquids Thiocyanate / isothiocyanate Borate Sulfonates / Sulfinates Selenium compounds Guanidine salt Borane Thiourea Thiolate tetrafluoroborate Thiol ester Polycyclic compound Crown ether Sulfone, sulfoxide compound Hydrazone Imide, amidine Polyamines Tosylate Epoxide Azide Hydroxylamine Cyclodextrin
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From early AD to mid-19 century, people mainly use the natural organic substance (such as animal and plant extracts) for qualitative analysis or quantitative analysis. From the second half of the 19th century to the 1920s, it had begun to appear of artificially synthetic organic reagent such as using potassium acetate xanthan for test of nickel, copper, and molybdenum; using morin for test of aluminum; using diazo coupling reaction for the detection of Nitrite; using α-β-nitroso naphthol for detection of cobalt; using dimethyglyoxime for nickel test.

After the proposal of the special-effects group in the 1930s and the proposal of theoretical analysis of functional groups theory in 1950s, people had carried out large-scale screen of organic reagents in search of special-effects analysis groups for different ions and had successfully synthesized a lot of agents of practical value (such as copper reagents, new copper agent, cadmium reagents, beryllium reagent, thorium reagents, etc.). Before the 1950s, the complex compound, in analytic chemistry, is mainly used in the aspects of the precipitation reaction of a binary chelate for the qualitative detection, precipitate isolation and gravimetric separation and other aspects. In the early 1950s and 1960, it is mainly in the form of complexometric titration. From the beginning of the late 1960s, the main focus has been moved to the photometric analysis. Meanwhile, it has been also developed of chelate organic solvent extraction.

8-hydroxy quinoline, hydrazones, oximes, hydroxamic acids, polyphenols, 1, 10-phenanthroline, phosphorus-oxygen extractant, β- diketones, triphenylmethane acid dye, xanthene dyes and azo dyes and other agents has all been widely studied and applied. On the other hand, the structural theoretical research (such as electronic effects, spatial effects and substituent effects) of the organic reagent can further facilitate the development of new-type organic reagents such as heterocyclic azo reagent. During this period, it has been also developed of monoazo chromotropic acid-type and disazo chromotropic acid-type reagent. During the mid-1970s, the chelating resin and adsorbents have achieved rapid development. Since the 1980s, Chinese researchers of analytical chemistry have made progress in the field of the synthesis and application of asymmetric disazo chromotropic acid.

Organic chemical reagents have wide application in analytic chemistry and are mainly used in solvents, precipitation agents, complexing agents, indicator, coloring reagent and surface active agent, etc. In order to adapt to a variety of analytical needs, sometimes it is required to purify certain reagents. For example, liquid organic reagent is often purified by distillation while solid substance is often purified through crystallization and sublimation. Substance having a high vapor pressure, namely having low purification boiling point and undergoing no decomposition under boiling temperature commonly applied atmospheric distillation; for less volatile and water-insoluble substance, namely having high purification point or undergoing decomposition under boiling temperature, we can apply vacuum distillation or steam distillation for purification of it.

Distillation is a commonly used method for laboratory purification of organic reagent. Conventional distillation apparatus generally comprises distiller, condenser and receiver, three parts with auxiliary section also containing heater, a thermometer, a wetted tube and cork.

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Structure:
Chemical Name:
6,7-dihydro-2-(2,4,6-trichlorophenyl)-5H-Pyrrolo[2,1-c]-1,2,4-triazolium tetrafluoroborate
CAS:
1353251-02-1
MF:
C11H9BCl3F4N3
Structure:
Chemical Name:
1,1,1-trifluoro-N-[(11bR)-4-oxido-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-Methanesulfonamide
CAS:
1239466-15-9
MF:
C51H57F3NO5PS
Structure:
Chemical Name:
Dicyclohexyl-t-butylphosphonium tetrafluoroborate
CAS:
1220349-00-7
MF:
C16H32BF4P
Structure:
Chemical Name:
3,3-Diphenylpropanol
CAS:
20017-67-8
MF:
C15H16O
Structure:
Chemical Name:
2-Bromo-4-tert-butyl-1-iodo-benzene
CAS:
860435-39-8
MF:
C10H12BrI
Structure:
Chemical Name:
Boronic acid, B-(6-phenyl-4-dibenzofuranyl)-
CAS:
1010068-85-5
MF:
C18H13BO3
Structure:
Chemical Name:
2-tert-Butyl-4,6-dimethylphenol
CAS:
1879-09-0
MF:
C12H18O
Structure:
Chemical Name:
(4-Fluoro-1H-indazol-6-yl)boronic acid
CAS:
1253911-24-8
MF:
C7H6BFN2O2
Structure:
Chemical Name:
4-Bromo-2-isopropylphenylboronic acid
CAS:
1451390-88-7
MF:
C9H12BBrO2
Structure:
Chemical Name:
benzo[c][1,2]oxaborole-1,5(3H)-diol
CAS:
1187190-70-0
MF:
C7H7BO3
Structure:
Chemical Name:
5-chloro-2-methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
CAS:
1621225-24-8
MF:
C12H17BClNO2
Structure:
Chemical Name:
4-Methoxybenzylhydrazine dihydrochloride
CAS:
412327-07-2
MF:
C8H14Cl2N2O
Chemical Name:
TRACKING DYE - 2D
Structure:
Chemical Name:
4-(3-CHLOROPROPYLCARBAMOYL)BENZENEBORONIC ACID
CAS:
874460-03-4
MF:
C10H13BClNO3
Structure:
Chemical Name:
2-(2-(2-Aminoethoxy)ethoxy)acetic acid
CAS:
134978-97-5
MF:
C6H13NO4
Structure:
Chemical Name:
6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)isoindolin-1-one
CAS:
1004294-80-7
MF:
C14H18BNO3
Structure:
Chemical Name:
Diisopropyl Allylboronate
CAS:
51851-79-7
MF:
C9H19BO2
Structure:
Chemical Name:
1,2-DIHYDRO-NAPHTHALENE-3-BORONIC ACID
CAS:
521917-51-1
MF:
C10H11BO2
Structure:
Chemical Name:
3-FLUORO-4-ISOPROPOXYPHENYLBORONIC ACID
CAS:
480438-54-8
MF:
C9H12BFO3
Structure:
Chemical Name:
ETHYLENE GLYCOL MONO-TERT-BUTYL ETHER
CAS:
7580-85-0
MF:
C6H14O2
Structure:
Chemical Name:
4-(1-PIPERIDINYL)PHENYLBORONIC ACID HCL
CAS:
229009-42-1
MF:
C11H16BNO2
Structure:
Chemical Name:
(6-FORMYLPYRIDIN-3-YL)BORONIC ACID
CAS:
1322001-30-8
MF:
C6H6BNO3
Structure:
Chemical Name:
benzylethyldimethylammonium chloride
CAS:
5197-80-8
MF:
C11H18ClN
Structure:
Chemical Name:
(2-chloro-2-oxo-1-phenylethyl)ammonium chloride
CAS:
5321-31-3
MF:
C8H9Cl2NO
Structure:
Chemical Name:
Benzoic acid, C12-15-alkyl esters
CAS:
68411-27-8
MF:
C19H30O2
Structure:
Chemical Name:
Methyl Tripropylammonium Chloride
MF:
C10H24ClN
Structure:
Chemical Name:
4-Carboxynaphthalene-1-boronic acid
CAS:
332398-57-9
MF:
C11H9BO4
Structure:
Chemical Name:
Methyl perfluoroisobutyl ether
CAS:
163702-08-7
MF:
C5H3F9O
Structure:
Chemical Name:
2,4-DIPROPOXYPHENYLBORONIC ACID
CAS:
150145-25-8
MF:
C12H19BO4
Structure:
Chemical Name:
2,2-Dimethylpropyltrifluoroborate potassium salt
CAS:
1150655-02-9
MF:
C5H11BF3K
Structure:
Chemical Name:
2,6-Difluoro-3-hydroxybenzeneboronic acid
CAS:
957065-86-0
MF:
C6H5BF2O3
Structure:
Chemical Name:
Dimethyldioctylammonium bromide
CAS:
3026-69-5
MF:
C18H40BrN
Structure:
Chemical Name:
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane
CAS:
78-63-7
MF:
C16H34O4
Structure:
Chemical Name:
7-Chlorobenzofuran
CAS:
24410-55-7
MF:
C8H5ClO
Structure:
Chemical Name:
3-(2-CYANOETHYLAMINOCARBONYL)PHENYLBORONIC ACID
CAS:
762262-11-3
MF:
C10H11BN2O3
Structure:
Chemical Name:
3-FORMYL-2-THIOPHENEBORONIC ACID
CAS:
17303-83-2
MF:
C5H5BO3S
Structure:
Chemical Name:
3-FORMYL-2-THIOPHENEBORONIC ACID
CAS:
17303-83-2
MF:
C5H5BO3S
Structure:
Chemical Name:
5-Carboxyfluorescein
CAS:
76823-03-5
MF:
C21H12O7
Structure:
Chemical Name:
(DODECYLBENZYL)TRIMETHYLAMMONIUM CHLORIDE
CAS:
1330-85-4
MF:
C22H40ClN
Structure:
Chemical Name:
Z-2-Buten-1-yl-boronic acid pinacol ester, Z-Crotylboronic acid pinacol ester, cis-2-(2-Buten-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS:
69611-01-4
MF:
C10H19BO2
Structure:
Chemical Name:
6-Methyl-2-phenyl-1,3,6,2-dioxazaborocane-4,8-dione
CAS:
109737-57-7
MF:
C11H12BNO4
Structure:
Chemical Name:
Ethyl 3-oxobutanoate sodium salt
CAS:
15933-07-0
MF:
C6H10O3
Structure:
Chemical Name:
Remitan
CAS:
6113-04-8
MF:
C21H28BrNO2
Structure:
Chemical Name:
(R)-4-CHLORO-3-HYDROXYBUTYRIC ACID METHYL ESTER
CAS:
88496-70-2
MF:
C5H9ClO3
Structure:
Chemical Name:
2-(Ethylsulfonyl)-5-(1-pyrrolidinyl)aniline
CAS:
1219972-54-9
MF:
C12H18N2O2S
Structure:
Chemical Name:
Choline tosylate
CAS:
55357-38-5
MF:
C12H21NO4S
Structure:
Chemical Name:
4-(Trimethylsilyl)thiophen-2-ylboronic acid
CAS:
222840-90-6
MF:
C7H13BO2SSi
Structure:
Chemical Name:
(3-boronophenyl)dimethylacetonitrile
CAS:
885067-95-8
MF:
C10H12BNO2
Structure:
Chemical Name:
4-Chloro-2-fluoro-3-hydroxyphenylboronic acid
CAS:
1451393-13-7
MF:
C6H5BClFO3
Structure:
Chemical Name:
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
CAS:
2386-87-0
MF:
C14H20O4
Structure:
Chemical Name:
3-Chloro-4-fluorophenylboronic acid pinacol ester
CAS:
635305-46-3
MF:
C12H15BClFO2
Chemical Name:
Ammonia - ammonium chloride Buffer Solution
Structure:
Chemical Name:
2,4-Dichloro-3-Methylacetophenone
CAS:
157652-32-9
MF:
C9H8Cl2O
Structure:
Chemical Name:
2-isopropoxypyridin-4-ylboronic acid
CAS:
1314239-18-3
MF:
C8H12BNO3
Structure:
Chemical Name:
Potassium ethyltrifluoroborate
CAS:
882871-21-8
MF:
C2H4BF3K
Structure:
Chemical Name:
4-*difluoro(3,4,5-trifluorophenoxy)-methyl]-3,5-difluoro-4'-propyl-1,1'-biphenyl
CAS:
303186-20-1
MF:
C22H15F7O
Structure:
Chemical Name:
2-Chloro-5-propoxyphenylboronic acid
CAS:
1256346-14-1
MF:
C9H12BClO3
Structure:
Chemical Name:
3-Isopropoxy-5-methylphenylboronic acid
CAS:
1256345-76-2
MF:
C10H15BO3
Structure:
Chemical Name:
3-Methyl-5-propoxyphenylboronic acid
CAS:
1256346-06-1
MF:
C10H15BO3
Structure:
Chemical Name:
4-(3-Fluorophenoxy)phenylboronic acid
CAS:
1029438-36-5
MF:
C12H10BFO3
Structure:
Chemical Name:
4,5-Dichloro-2-(2-methoxyethoxy)phenylboronic acid
CAS:
1256354-99-0
MF:
C9H11BCl2O4
Structure:
Chemical Name:
Iodomethylboronic acid, pinacol ester
CAS:
70557-99-2
MF:
C7H14BIO2
Structure:
Chemical Name:
Cyclobutylboronic acid MIDA ester
CAS:
1104637-37-7
MF:
C9H14BNO4
Structure:
Chemical Name:
4,4,5,5-Tetramethyl-2-(1-propyn-1-yl)-1,3,2-dioxaborolane
CAS:
347389-75-7
MF:
C9H15BO2
Structure:
Chemical Name:
3-(1-phenyl-1H-benzo[d]iMidazol-2-yl)phenylboronic acid
CAS:
1214723-26-8
MF:
C19H15BN2O2
Chemical Name:
Cetrimide Agar
Structure:
Chemical Name:
2-(MethylcarbaMoyl)benzeneboronic acid
CAS:
874459-85-5
MF:
C8H10BNO3
Structure:
Chemical Name:
BenzenaMine, 5-chloro-2-fluoro-3-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-
CAS:
1269232-96-3
MF:
C12H16BClFNO2
Structure:
Chemical Name:
1,2,4,5-Tetrakis(4-carboxyphenyl)benzene
CAS:
1078153-58-8
MF:
C34H22O8
Structure:
Chemical Name:
1-Boc-indole-4-boronic Acid Pinacol Ester
CAS:
893441-86-6
MF:
C19H26BNO4
Structure:
Chemical Name:
4-Formyl-2,6-dimethylphenylboronic acid
CAS:
1228829-13-7
MF:
C9H11BO3
Structure:
Chemical Name:
[4-Methyl-2-(1H-pyrazol-1-yl)phenyl]boronic acid
CAS:
1287753-43-8
MF:
C10H11BN2O2
Structure:
Chemical Name:
6-Borono-3-chloroisoquinoline, 6-Borono-3-chloro-2-azanaphthalene
CAS:
1800483-72-0
MF:
C9H7BClNO2
Structure:
Chemical Name:
PGUQU 3F
CAS:
303186-36-9
MF:
C28H18F8O
Structure:
Chemical Name:
(3-(p-tolylcarbaMoyl)phenyl)boronic acid
CAS:
1072946-03-2
MF:
C14H14BNO3
Structure:
Chemical Name:
1426129-50-1 enantioMer
CAS:
153037-40-2
MF:
C20H25NO3
Chemical Name:
Hydroxyl-terminated polybutadiene
CAS:
69102-90-5
Structure:
Chemical Name:
4-(Azetidine-1-carbonyl)phenylboronic Acid
CAS:
1025664-35-0
MF:
C10H12BNO3
Structure:
Chemical Name:
9-Phenanthreneboronic acid neopentylglycol ester
CAS:
1416371-19-1
MF:
C19H19BO2
Structure:
Chemical Name:
Dodecylethyldimethylammonium bromide
CAS:
68207-00-1
MF:
C16H36BrN
Structure:
Chemical Name:
4-(N-OCTYL)BENZENEBORONIC ACID
CAS:
133997-05-4
MF:
C14H23BO2
Structure:
Chemical Name:
Trityl tetrakis(pentafluorophenyl)borate
CAS:
136040-19-2
MF:
C43H15BF20
Structure:
Chemical Name:
5-Fluoro-2-hydroxypyridine-4-boronic acid
CAS:
1427305-76-7
MF:
C5H5BFNO3
Structure:
Chemical Name:
2,5-BIS(TRIFLUOROMETHYL)BENZENEBORONIC ACID
CAS:
196083-18-8
MF:
C8H5BF6O2
Structure:
Chemical Name:
Triphenylsulfonium 10-Camphorsulfonate
CAS:
227199-92-0
MF:
C28H30O4S2
Structure:
Chemical Name:
2,1,3-Benzothiadiazole-4,7-diboronic acid
CAS:
1332458-85-1
MF:
C6H6B2N2O4S
Structure:
Chemical Name:
4-ETHOXYBIPHENYL-4'-BORONIC ACID
CAS:
182344-29-2
MF:
C14H15BO3
Structure:
Chemical Name:
BENZYLDIMETHYLSTEARYLAMMONIUM CHLORIDE
CAS:
206752-43-4
MF:
C6H5CH2N[(CH2)17CH3](CH3)2ClH2O
Structure:
Chemical Name:
METHYL 3-(4 4 5 5-TETRAMETHYL-1 3 2-DIO&
CAS:
352534-74-8
MF:
C15H27BO4
Structure:
Chemical Name:
Tianeptine
CAS:
72797-41-2
MF:
C21H25ClN2O4S
Structure:
Chemical Name:
2-ETHOXY-3-FORMYL-5-METHYLPHENYLBORONIC
CAS:
480424-54-2
MF:
C10H13BO4
Structure:
Chemical Name:
TRIPHENYLPHOSPHINE(2 5-NORBORNADIENE)RH&
CAS:
305367-01-5
MF:
C25H23BF4PRh-
Structure:
Chemical Name:
TRANS-3-PHENYL-1-PROPEN-1-YLBORONIC ACID
CAS:
129423-29-6
MF:
C9H11BO2
Structure:
Chemical Name:
Boronic acid, B,B'-[5''-(4'-borono[1,1'-biphenyl]-4-yl)[1,1':4',1'':3'',1''':4''',1''''-quinquephenyl]-4,4''''-diyl]bis-
CAS:
1290630-80-6
MF:
C42H33B3O6
Chemical Name:
Wuhan ethylene glycol
Chemical Name:
NA
Chemical Name:
Crystal Violet Methanol Solution
Chemical Name:
NA
Structure:
Chemical Name:
TRIETHYLMETHYLAMMONIUM HYDROXIDE
CAS:
109334-81-8
MF:
C7H19NO
Structure:
Chemical Name:
2-CHLORO-5-(TRIFLUOROMETHOXY)PHENYLBORONIC ACID
CAS:
1022922-16-2
MF:
C7H5BClF3O3