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5-Bromo-2-hydroxymethylpyridine

Product Name
5-Bromo-2-hydroxymethylpyridine
CAS No.
88139-91-7
Chemical Name
5-Bromo-2-hydroxymethylpyridine
Synonyms
(5-BROMO-PYRIDIN-2-YL)-METHANOL;5-Bromo-2-pyridinemethanol;(5-Bromo-2-pyridyl)methanol;(5-BROMOPYRID-2-YL)METHANOL;2-Pyridinemethanol, 5-bromo-;5-Bromo-2-pyridinemethanol >5-Bromo-2-hydroxymethylpyridin;5-BROMO-2-HYDROXYMETHYLPYRIDINE;2-HYDROXYMETHYL-5-BROMOPYRIDINE;(5-Bromopyridin-2-yl)methanol ,98%
CBNumber
CB0457585
Molecular Formula
C6H6BrNO
Formula Weight
188.02
MOL File
88139-91-7.mol
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5-Bromo-2-hydroxymethylpyridine Property

Melting point:
59-60°C
Boiling point:
0°C
Density 
1.668±0.06 g/cm3(Predicted)
Flash point:
0°C
storage temp. 
Inert atmosphere,Room Temperature
form 
powder to crystal
pka
13.09±0.10(Predicted)
color 
White to Light yellow to Light orange
InChI
InChI=1S/C6H6BrNO/c7-5-1-2-6(4-9)8-3-5/h1-3,9H,4H2
InChIKey
RUCZFWMEACWFER-UHFFFAOYSA-N
SMILES
C1(CO)=NC=C(Br)C=C1
CAS DataBase Reference
88139-91-7(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38-22
Safety Statements 
22-26-36/37/39-36
HazardClass 
IRRITANT
HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3492
Product name
5-Bromo-2-pyridinemethanol
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$48
Updated
2024/03/01
TCI Chemical
Product number
B3492
Product name
5-Bromo-2-pyridinemethanol
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$145
Updated
2024/03/01
TRC
Product number
B696208
Product name
5-Bromo-2-hydroxymethylpyridine
Packaging
250mg
Price
$55
Updated
2021/12/16
Oakwood
Product number
036351
Product name
(5-Bromo-pyridin-2-yl)-methanol
Purity
97%
Packaging
5g
Price
$40
Updated
2021/12/16
Matrix Scientific
Product number
016549
Product name
5-Bromo-2-(hydroxymethyl)pyridine
Purity
97%
Packaging
5g
Price
$40
Updated
2021/12/16
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5-Bromo-2-hydroxymethylpyridine Chemical Properties,Usage,Production

Chemical Properties

Light yellow Cryst

Synthesis

5-bromo-2-pyridinecarboxylic acid, methyl ester (648mg, 3mmol) in 10ml of methanol was slowly added to sodium borohydride (340mg, 9mmol) in an ice bath. After that, the ice bath was removed and the reaction mixture was warmed to room temperature. The reaction was stirred for 12 hours. Then 1N HCl was added to adjust the pH to 1. Afterward, a saturated sodium bicarbonate solution was added to adjust the pH to 8. The mixture was then extracted with ethyl acetate. The organic phase was dried over anhydrous magnesium sulfate, filtered, and concentrated under reduced pressure. This resulted in the formation of 535mg of white solid, which was identified as 5-bromo-2-pyridinemethanol. The yield of the desired product was 94.8%.

5-Bromo-2-hydroxymethylpyridine Preparation Products And Raw materials

Raw materials

3-Chloroperoxybenzoic acid Chloroform Trifluoroacetic anhydride Diethyl ether Ethyl acetate 5-Bromo-2-methylpyridine Sodium bicarbonate Methanol Sodium thiosulfate pentahydrate Sodium carbonate

Preparation Products

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5-Bromo-2-hydroxymethylpyridine Suppliers

Americas 1 Belgium 1 China 243 Europe 3 Germany 2 India 4 Japan 1 Switzerland 1 The Netherlands 1 United Kingdom 10 United States 29 Global 296
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
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View Lastest Price from 5-Bromo-2-hydroxymethylpyridine manufacturers

Hebei Mojin Biotechnology Co.,Ltd
Product
2-Hydroxymethyl-5-bromopyridine 88139-91-7
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50000KG/month
Release date
2024-08-30
Henan Aochuang Chemical Co.,Ltd.
Product
2-Hydroxymethyl-5-bromopyridine 88139-91-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-08
Dideu Industries Group Limited
Product
2-Hydroxymethyl-5-bromopyridine 88139-91-7
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons min
Release date
2021-08-25

88139-91-7, 5-Bromo-2-hydroxymethylpyridineRelated Search:

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