Benzhydrylamine

Product Name: Benzhydrylamine
CAS No.: 91-00-9
Chemical Name: Benzhydrylamine
Synonyms: BENZHYDRYLAMINE;1,1-Diphenylmethanamine;NSC 49127;AURORA KA-7667;Benzyldrylamine;Benzhydralamine;benzohydrylamine;Benzylhydrylamine;a-Phenylbenzylamine;diphenylMethylaMino
CBNumber: CB7409604
Molecular Formula: C13H13N
Formula Weight: 183.25
MOL File: 91-00-9.mol

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Benzhydrylamine Property

Melting point:: 12 °C (lit.)
Boiling point:: 295 °C (lit.)
Density: 1.063 g/mL at 25 °C (lit.)
refractive index: n20/D 1.595(lit.)
Flash point:: >230 °F
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
solubility: Chloroform, DMSO, Methanol
pka: 8.41±0.10(Predicted)
form: Liquid
color: Clear colorless to yellow
Specific Gravity: 1.063
Water Solubility: Miscible with chloroform, dimethylsulfoxide and methanol. Slightly miscible with water.
Sensitive: Air Sensitive
Merck: 14,1076
BRN: 776434
CAS DataBase Reference: 91-00-9(CAS DataBase Reference)
NIST Chemistry Reference: Aminodiphenylmethane(91-00-9)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-36/37/38
Safety Statements: 26-36
RIDADR: 2810
WGK Germany: 3
RTECS: DA4407300
F: 9-23
HazardClass: 8
PackingGroup: III
HS Code: 29214990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: A53605
Product name: Benzhydrylamine
Purity: 97%
Packaging: 5g
Price: $44.3
Updated: 2025/07/31

Sigma-Aldrich

Product number: A53605
Product name: Benzhydrylamine
Purity: 97%
Packaging: 25g
Price: $45.2
Updated: 2025/07/31

TCI Chemical

Product number: B0124
Product name: Benzhydrylamine
Purity: >97.0%(GC)(T)
Packaging: 25mL
Price: $37
Updated: 2025/07/31

TCI Chemical

Product number: B0124
Product name: Benzhydrylamine
Purity: >97.0%(GC)(T)
Packaging: 100mL
Price: $104
Updated: 2025/07/31

Sigma-Aldrich

Product number: A53605
Product name: Benzhydrylamine
Purity: 97%
Packaging: 100g
Price: $144
Updated: 2025/07/31

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Benzhydrylamine Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

Benzhydrylamine is fine-chemical intermediate used for chiral resolution. It acts as an active pharmaceutical ingredient intermediate. It is also employed as a building block for chemical synthesis. Further, it is used in the preparation of furan-2-carboxylic acid benzhydrylamide by reacting with furan-2-carbonyl chloride.

Synthesis Reference(s)

Tetrahedron Letters, 27, p. 3033, 1986 DOI: 10.1016/S0040-4039(00)84709-7

Synthesis

1) synthesis of diphenylketoxime
After benzophenone 10g, oxammonium hydrochloride 6g, 95% ethanol 20mL are put into reaction flask stirring and dissolving, gradation adds sodium hydrate solid 11g.Finish, reaction solution is heated to 88°C of reaction 2h, then pours in dilute hydrochloric acid solution by reaction solution, occurs white solid, filter to obtain diphenylketoxime 10.7g, yield 99%.
2) synthesis of benzhydrylamine
Diphenylketoxime 0.25g, 95% ethanol 5mL are put into reaction flask, after solution change is clear, adds concentration into 5 × 10 7cFU/mL waxy Bacillus solution 50mL, constant temperature 30°C (rotating speed 200r/min) oscillatory reaction in shaking table.TLC detect without raw material time, add appropriate diatomite in reaction solution and carry out centrifugation, get supernatant liquid acidifying, with dichloromethane extraction, aqueous layer basified and with dichloromethane extraction concentrate to obtain benzhydrylamine 9.0g, yield 91%.

Purification Methods

Crystallise the amine from H2O. The free base absorbs CO2 from the atmosphere; store it accordingly. The hydrochloride M 219.7 m 293-295o, crystallises from H2O. [Beilstein 12 H 1323, 12 IV 3282.]

Benzhydrylamine Preparation Products And Raw materials

Raw materials

Preparation Products

3-Hydroxyazetidine hydrochloride AURAMINE O 1-Boc-3-(Amino)azetidine Azetidin-3-ol 3-N-Boc-amino-azetidine Nafarelin 4-Aminobenzamidine dihydrochloride Azetidine 1-Benzhydrylazetidine-3-carboxylic acid 1-Boc-hexahydro-1,4-diazepine Azetidine hydrochloride

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Benzhydrylamine Suppliers

Americas 1 Austria 1 Belgium 1 Canada 2 China 370 Europe 4 France 2 Germany 8 India 38 Ireland 1 Italy 1 Japan 6 Slovakia 1 South Korea 1 Switzerland 2 The Netherlands 2 United Kingdom 18 United States 50 Global 509

Zibo Litaiyu Trading Co., Ltd.

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Email: 894721584@qq.com
Country: China
ProdList: 8
Advantage: 58

CE Pharm Co.,Ltd

Tel: 15317222985
Fax: binbin.lin@cepharm.cn
Email: bingna.wang@cepharm.cn
Country: China
ProdList: 154
Advantage: 58

Nantong Xiaochang Pharmaceutical Trading Co., Ltd.

Tel: 0513-82104991 15716298013
Fax: QQ1907456386
Email: sales11@btcpharm.com
Country: China
ProdList: 1221
Advantage: 58

BTC Pharmaceutical CO. Ltd

Tel: 15716293042 18862996710
Fax: 0513-68015394
Email: 15050603958@163.com
Country: China
ProdList: 691
Advantage: 55

Shandong Lierbang New Material Co. LTD

Tel: 15553337722
Email: 1135818881@qq.com
Country: China
ProdList: 31
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Shandong Jialian New Materials Co., Ltd

Tel: 18560999950; 18560999950
Email: 905978557@qq.com
Country: China
ProdList: 20
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259138 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

INTATRADE GmbH

Tel: +49 3493/605464
Fax: +49 3493/605470
Email: sales@intatrade.de
Country: Germany
ProdList: 3572
Advantage: 66

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

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View Lastest Price from Benzhydrylamine manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: Aminodiphenylmethane 91-00-9
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100 mt
Release date: 2025-03-10

Henan Aochuang Chemical Co.,Ltd.

Product: Aminodiphenylmethane 91-00-9
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-18

Sichuan Zhuoyu Yantang Technology Co., Ltd.

Product: Aminodiphenylmethane 91-00-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-25

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