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Analytical Chemistry

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Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Chemical Name:
Atracurium Impurity E
Chemical Name:
Linagliptin Impurity I
Structure:
Chemical Name:
1H-Pyrrole-3-carbonitrile,5-(2-fluorophenyl)-1-(3-pyridinylsulfonyl)-
CAS:
1807642-39-2
MF:
C16H10FN3O2S
Structure:
Chemical Name:
4-amino-1-[(2RS)-2-(2,4-difluorophenyl)-2-hydroxy-3(1H- 1,2,4-triazol-1-yl)propyl]-4H-1,2,4-triazolium
CAS:
749821-19-0
MF:
C13H14F2N7O+
Chemical Name:
Canagliflozin Defluoro Impurity
Chemical Name:
Dapagliflozin Impurity 6
Structure:
Chemical Name:
Imatinib Impurity 7
CAS:
581076-64-4
MF:
C8H12N4
Structure:
Chemical Name:
Nilotinib Impurity 1
CAS:
641571-05-3
MF:
C28H22F3N7O
Chemical Name:
Riociguat Impurtiy 1
Structure:
Chemical Name:
Riociguat Impurtiy 6
CAS:
1702271-98-4
MF:
C18H17FN8
Structure:
Chemical Name:
Axitinib Impurity 4
CAS:
1443118-73-7
MF:
C22H20N4OS
Structure:
Chemical Name:
Brimonidine Impurity E
CAS:
168329-48-4
MF:
C9H8BrN5
Chemical Name:
Dapagliflozin Impurity G
Chemical Name:
Dapoxetine Impurity B
Chemical Name:
Esomeprazole EP Impurity
Structure:
Chemical Name:
Fesoterodine Diol Dimer
CAS:
1428856-45-4
MF:
C44H60N2O3
Structure:
Chemical Name:
Gimeracil Impurity
CAS:
17902-24-8
MF:
C8H9ClN2O3
Chemical Name:
Pramipexole Impurity H
Structure:
Chemical Name:
Quercetin 3-rutinoside 7-glucoside
CAS:
30311-61-6
MF:
C33H40O21
Structure:
Chemical Name:
Rivaroxaban Impurity H
CAS:
1807455-76-0
MF:
C25H24Cl2N4O6S2
Chemical Name:
Vonoprazan impurity A
Structure:
Chemical Name:
34-Methylcyanocobalamin
CAS:
38218-51-8
MF:
C64H90CoN14O14P
Chemical Name:
Empagliflozin Impurity D
Chemical Name:
Ipragliflozin Impurity 2
Chemical Name:
Nicergoline EP impurity F
Chemical Name:
Mirabegron Impurity 4
Structure:
Chemical Name:
Bisoprolol EP Impurity D
CAS:
1225195-71-0
MF:
C26H40N2O5
Structure:
Chemical Name:
Febuxostat Descyano Impurity
CAS:
1206550-99-3
MF:
C15H17NO3S
Structure:
Chemical Name:
(5S,8R,9S,10S,13S,14S)-10,13-dimethyl-1,5,6,7,8,9,10,11,12,13,15,16-dodecahydro-4H-cyclopenta[a]phenanthren-17(14H)-one
CAS:
14639-79-3
MF:
C19H28O
Structure:
Chemical Name:
Cefuroxime Sodium Impurity
MF:
C16H16N4NaO8S
Structure:
Chemical Name:
5-chloro-6-[4-(ethoxycarbonyl)piperidino]nicotinic acid
CAS:
931395-73-2
MF:
C14H17ClN2O4
Structure:
Chemical Name:
2-Bromo (S)-Carbidopa
CAS:
43197-33-7
MF:
C10H13BrN2O4
Structure:
Chemical Name:
Eliglustat intermediate 3
CAS:
491833-26-2
MF:
C23H28N2O5
Structure:
Chemical Name:
Aztreonam Impurity B
CAS:
102586-36-7
MF:
C13H19N5O6S
Structure:
Chemical Name:
Atorvastatin Impurity 30
CAS:
666714-64-3
MF:
C26H23FN2O
Chemical Name:
Olopatadine impurity
Structure:
Chemical Name:
Azilsartan Impurity
CAS:
1863930-34-0
MF:
C23H23N3O3
Structure:
Chemical Name:
Voriconazole Impurity 8
CAS:
239807-03-5
MF:
C16H14F3N5O
Chemical Name:
Caspofungin impurity 3
Chemical Name:
Plerixafor Impurity D
Structure:
Chemical Name:
Cefuroxime impurity 1
MF:
C16H16N4O8S
Chemical Name:
Vonoprazan Impurity 9
Chemical Name:
Sitagliptin IMpurity 5
Chemical Name:
Brexpiprazole Impurity3
Structure:
Chemical Name:
Levetiracetam impurity 5
CAS:
1543300-90-8
MF:
C9H17NO4
Chemical Name:
Febuxostat Impurity B
Chemical Name:
Sorafenib Impurity F
Structure:
Chemical Name:
Trelagliptin Impurity 1
CAS:
1821400-07-0
MF:
C21H13ClF2N4O2
Structure:
Chemical Name:
Vortioxetine Imp.J
CAS:
2137588-68-0
MF:
C18H22N2S
Structure:
Chemical Name:
4-amino-N-(1-(3-methoxypropyl)piperidin-4-yl)-2,3-dihydrobenzofuran-7-carboxamide
CAS:
1608459-56-8
MF:
C18H27N3O3
Structure:
Chemical Name:
4,5-dichloro Rivaroxaban
CAS:
2305917-61-5
MF:
C25H28ClN3O6S
Structure:
Chemical Name:
Solifenacin EP Impurity B
CAS:
1534326-81-2
MF:
C31H28N2O
Structure:
Chemical Name:
Vildagliptin Impurity 6
CAS:
1846606-31-2
MF:
C17H23N3O2
Chemical Name:
Flucloxacillin Impurity A
Structure:
Chemical Name:
Zolmitriptan Related Compound B (20 mg) ((S)-2-Amino-3-{3-[2-(dimethylamino)ethyl]-1H-indol-5-yl}propan-1-ol)
CAS:
139264-69-0
MF:
C15H23N3O
Structure:
Chemical Name:
1-BENZYL-N,4-DIMETHYLPIPERIDIN-3-AMINE DIHYDROCHLORIDE
CAS:
384338-23-2
MF:
C14H22N2
Structure:
Chemical Name:
Palonosetron Impurity 7
CAS:
177932-92-2
MF:
C18H24N2O
Structure:
Chemical Name:
4-(2,3-Dichlorophenyl)-2,6-diMethyl-1,4-dihydropyridine-3,5-dicarboxylic acid
CAS:
138279-32-0
MF:
C15H13Cl2NO4
Chemical Name:
IMp. A (EP) as Hydrochloride: 3-[[[2-[(DiaMinoMethylene)aMino]thiazol-4-yl]- Methyl]sulphanyl]propaniMidaMide Hydrochloride
Structure:
Chemical Name:
2-(MethylcarbaMoyl)benzoic acid
CAS:
6843-36-3
MF:
C9H9NO3
Structure:
Chemical Name:
1-(4-(2-Methoxyethyl)phenoxy)-3-(oxiran-2-ylMethoxy)propan-2-ol
CAS:
1416440-64-6
MF:
C15H22O5
Structure:
Chemical Name:
(3S,4S)-1-benzyl-N,4-diMethylpiperidin-3-aMine
CAS:
1354621-59-2
MF:
C14H22N2
Structure:
Chemical Name:
1H-BenziMidazole-7-carboxylic acid, 1-[[2'-(2,5-dihydro-5-oxo-1,2,4-oxadiazol-3-yl)[1,1'-biphenyl]-4-yl]Methyl] -2-ethoxy-, ethyl ester
CAS:
1403474-70-3
MF:
C27H24N4O5
Structure:
Chemical Name:
6-acetyl-2-aMino-8-cyclopentyl-5-Methylpyrido[2,3-d]pyriMidin-7(8H)-one
CAS:
571189-64-5
MF:
C15H18N4O2
Structure:
Chemical Name:
Apixaban-13C-D3
CAS:
1261393-15-0
MF:
C2413CH22D3N5O4
Chemical Name:
IMp. C (EP): Ethyl [(4-Methylphenyl)sulphonyl]-CarbaMate
Chemical Name:
IMp. C (EP): Methyl-2-[4-[2-[(4-Chlorobenzoyl)aMino]ethyl]phenoxy]-2-Methylpropanoate
Structure:
Chemical Name:
5-PyriMidinecarboxylic acid, 4-(4-fluorophenyl)-1,2-dihydro-6-(1-Methylethyl)-2-oxo-, Methyl ester
CAS:
488798-37-4
MF:
C15H15FN2O3
Chemical Name:
Nebivolol O-Beta-D-Glucuronide
Chemical Name:
Nicergoline IMp. C (EP)
Chemical Name:
Perindopril IMpurity E
Structure:
Chemical Name:
Pitavastatin 3-Oxo SodiuM
CAS:
2245811-12-3
MF:
C25H22FNO4
Structure:
Chemical Name:
PraMipexole IMp.BI-II828BS
MF:
C20H32N6S2
Chemical Name:
Propofol IMpurity F
Structure:
Chemical Name:
Rosuvastatin IMpurity SodiuM Salt (5-Oxo Rosuvastatin SodiuM Salt)
CAS:
1422619-13-3
MF:
C22H26FN3O6S
Structure:
Chemical Name:
Sertraline IMpurity (SRTRC-3)
MF:
C17H17Cl2N
Structure:
Chemical Name:
Terbutaline IMpurity B
CAS:
94120-05-5
MF:
C13H19NO3
Structure:
Chemical Name:
Benzoic acid, 4-[(4-Methyl-1-piperazinyl)Methyl]-3-(trifluoroMethyl)-
CAS:
859282-11-4
MF:
C14H17F3N2O2
Structure:
Chemical Name:
N-(5-Chloropyridin-2-yl)oxalaMic acid ethyl ester
CAS:
349125-08-2
MF:
C9H9ClN2O3
Structure:
Chemical Name:
5-chloro-2,3-diphenylpyrazine
CAS:
41270-66-0
MF:
C16H11ClN2
Structure:
Chemical Name:
Desfluoro Rosuvastatin Sodium Salt
CAS:
847849-66-5
MF:
C22H29N3O6S
Structure:
Chemical Name:
N-Benzoyl-N-[2-(phenyl)ethyl]-N-carbamic Acid R-Quinuclidinol Ester Succinic Acid Salt
CAS:
1798817-92-1
MF:
C27H32N2O7
Chemical Name:
Tadalafil EP IMpurity A
Structure:
Chemical Name:
(1R,3R,4R)-3-AMino-4-hydroxy-cyclohexanecarboxylic acid ethyl ester
CAS:
1392745-70-8
MF:
C14H25NO5
Structure:
Chemical Name:
(S)-3-Hydroxypiperidine
CAS:
24211-55-0
MF:
C5H11NO
Chemical Name:
Aprepitant iMpurity B
Structure:
Chemical Name:
Aripiprazole iMpurity 4
CAS:
1424857-63-5
MF:
C36H42Cl2N4O4
Chemical Name:
Avanafil IMpurity 8 (R-Avanafil)
Structure:
Chemical Name:
EzetiMibe ring-opening dehydrate iMpurity
CAS:
1292292-63-7
MF:
C24H21F2NO3
Structure:
Chemical Name:
Fondaparinux sodiuM iMpurity 1
CAS:
348625-84-3
MF:
C13H21NO19S3
Structure:
Chemical Name:
Pitavastatin IMpurity 4 (PP-4)
CAS:
1422058-54-5
MF:
C25H22FNO3
Structure:
Chemical Name:
Pregabalin IMpurity
CAS:
159029-27-3
MF:
C7H18N2
Structure:
Chemical Name:
Valdecoxib 3'-SulfonaMide IMpurity
CAS:
1373038-56-2
MF:
C16H14N2O3S
Structure:
Chemical Name:
(3R,4R)-4-(2,5-Difluorophenyl)-3-Methyl-4-(1H-1,2,4-triazol-1-ylMethyl)-2-oxetanone
CAS:
483340-20-1
MF:
C13H11F2N3O2
Structure:
Chemical Name:
6,7-DiMethoxy-2-(4-(tetrahydrofuran-2-carbonyl)piperazin-1-yl)quinazolin-4(1H)-one
CAS:
1177261-73-2
MF:
C19H24N4O5
Structure:
Chemical Name:
2-Hydroxy Atorvastatin Calcium Salt
CAS:
265989-46-6
MF:
C33H37CaFN2O6
Structure:
Chemical Name:
13-oxo-1,4,7,10-Tetraazabicyclo[8.2.1]tridecane-4,7-diacetic Acid
CAS:
229312-33-8
MF:
C13H22N4O5
Structure:
Chemical Name:
rac-Clopidogrel Carboxylic Acid Hydrochloride
CAS:
1015247-88-7
MF:
C15H15Cl2NO2S
Structure:
Chemical Name:
Milnacipran IMpurity
CAS:
810696-16-3
MF:
C11H11NO
Structure:
Chemical Name:
Terbutaline IMpurity 8
CAS:
28924-20-1
MF:
C26H30BrNO3