Uses
ChemicalBook > CAS DataBase List > 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,

1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,

Uses
Product Name
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
CAS No.
95408-45-0
Chemical Name
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
Synonyms
Pd(dtbpf)Cl2;PdCl2(dtbpf);[1,1'-Bis(di-tert-butyL;1,1'-Bis (di-t-butylphosphino);PdCl2(dtbpf) , Product of UMicore;[1,1'-Bis(di-tert-butylphosphino);PdCl2(dtbpf), 15% Pd, Product of UMicore;PdCl2(dtbpf), 16% Pd, Product of Umicore;Dichloro[1,1-Bis(Di-Tert-Butylphosphino);[1,1'-Bis(di-tert-butylphosphino)ferrocene]dichlor
CBNumber
CB0947350
Molecular Formula
C26H38Cl2FeP2Pd
Formula Weight
645.7
MOL File
95408-45-0.mol
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1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Property

Melting point:
203-208 °C
storage temp. 
-20°C
solubility 
Soluble in dichloromethane and chloroform. Partially soluble in acetone, alcohols, tertrahydrofuran and dioxane.
form 
crystal
color 
dark purple
InChI
InChI=1S/2C13H19P.2ClH.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h2*14H,1-6H3;2*1H;;/q;;;;+2;/p-2
InChIKey
ORDFDLUOXDTTTD-UHFFFAOYSA-L
SMILES
C(P1([Pd+2](P(C(C)(C)C)(C(C)(C)C)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]18C9=3)([Cl-])[Cl-])C(C)(C)C)(C)(C)C
CAS DataBase Reference
95408-45-0
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Safety

Safety Statements 
24/25
WGK Germany 
3
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
701602
Product name
[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)
Purity
98%
Packaging
1g
Price
$268
Updated
2024/03/01
Sigma-Aldrich
Product number
701602
Product name
[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)
Purity
98%
Packaging
5g
Price
$1070
Updated
2024/03/01
TCI Chemical
Product number
B3160
Product name
[1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II) Dichloride
Purity
>98.0%(T)
Packaging
1g
Price
$153
Updated
2024/03/01
TCI Chemical
Product number
B3160
Product name
[1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II) Dichloride
Purity
>98.0%(T)
Packaging
5g
Price
$597
Updated
2024/03/01
Alfa Aesar
Product number
044829
Product name
Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II), Pd 16.3%
Packaging
0.1g
Price
$86.5
Updated
2023/06/20
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1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Chemical Properties,Usage,Production

Uses

[1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) may be used as catalyst in the Suzuki cross-coupling reaction of various aromatic and heteroaromatic halides with methyliminodiacetic acid derivatives.

Chemical Properties

reddish brown crystal

Uses

suzuki reaction

Uses

Coupling reactions, Suzuki couplings.Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene] palladium(II) is used as a catalyst in Suzuki-cross coupling reactions, which involve reaction of aromatic halides with methyliminodiacetic acid derivatives. it is also used as a catalyst for the preparation of chalcones. It is used in the preparation of (bisphosphinometallocene)-palladium(II) chloride complexes, which used as a starting material for the Buchwald-Hartwig reaction.

Uses

1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride is used as a catalyst for the preparation of chalcones.

General Description

This product has been enhanced for catalytic efficiency.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Preparation Products And Raw materials

Raw materials

Bromocyclohexane 2-Butanol Ferrocene Hexane Acetonitrile Di-tert-butylchlorophosphane N,N,N',N'-Tetramethylethylenediamine 2-Chloro-2-methylpropane Cyclohexane Toluene 2,2'-Bipyridine Cinchonidine Phosphorus trichloride Tetrahydrofuran Palladium chloride Ethyl acetate Dichloromethane Magnesium n-Butyllithium

Preparation Products

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1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Suppliers

Americas 1 Australia 1 Belgium 1 China 233 Europe 1 India 4 Japan 1 South Korea 1 Switzerland 1 United Kingdom 2 United States 15 Global 261
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View Lastest Price from 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, manufacturers

Shanghai Daken Advanced Materials Co.,Ltd
Product
[1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 95408-45-0
Price
US $0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG /month
Release date
2021-11-11
Shaanxi Dideu Medichem Co. Ltd
Product
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride 95408-45-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2020-04-17
Zhuozhou Wenxi import and Export Co., Ltd
Product
[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 95408-45-0
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

95408-45-0, 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Related Search:

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  • 1,1′-Bis-(di-tert.-butylphosphino-)ferrocen-palladiumdichlorid, PdCl2(dtbpf)
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  • Dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II),98%
  • 95408-45-0
  • C26H44FeP2PdCl2
  • ditbpfPdCl2
  • C5H4PC4H922FePdCl2
  • C26H46Cl2FeP2Pd
  • C26H44Cl2FeP2Pd
  • 2C13H22PCl2PdFe
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