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Analytical Chemistry

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Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Chemical Name:
Rivaroxaban Impurity 23
Structure:
Chemical Name:
(Z)-2-(2-aminothiazol-4-yl)-2-(hydroxyimino)acetamide
CAS:
1450758-21-0
MF:
C5H6N4O2S
Structure:
Chemical Name:
Fosfomycin Trometamol impurity C
CAS:
23001-39-0
MF:
C4H12NO6P
Structure:
Chemical Name:
(R)-1-(3-(dimethylamino)propyl)-1-(4-fluorophenyl)-1,3-dihydroisobenzofuran-5-carbonitrile oxalate
MF:
C22H23FN2O5
Structure:
Chemical Name:
3-((3S,4R)-4-Methyl-3-(Methyl(7H-pyrrolo[2,3-d]pyriMidin-4-yl)aMino)piperidin-1-yl)-3-oxopropanenitrile
CAS:
1092578-48-7
MF:
C16H20N6O
Structure:
Chemical Name:
4-aMino-5-chloro-2,3-dihydro-N-4-piperidinyl-7-BenzofurancarboxaMide
CAS:
137211-64-4
MF:
C14H18ClN3O2
Structure:
Chemical Name:
ClotriMazole IMpurity A
CAS:
23593-71-7
MF:
C22H17ClN2
Structure:
Chemical Name:
9-Nitrominocycline
CAS:
149934-16-7
MF:
C23H26N4O9
Structure:
Chemical Name:
N-(3,5-DiMethyladaMantan-1-yl)forMaMide
CAS:
351329-88-9
MF:
C13H21NO
Structure:
Chemical Name:
N-(Methylsulfonyl)-4'-nitro-2'-phenoxyMethanesulfonanilide
CAS:
51765-72-1
MF:
C14H14N2O7S2
Structure:
Chemical Name:
Olanzapine ThioacetoxyMethylidene IMpurity Discontinued
CAS:
1320360-87-9
MF:
C17H20N4O2S
Structure:
Chemical Name:
1-NaphthaleneethanaMine, 7-Methoxy-N-[2-(7-Methoxy-1-naphthalenyl)ethyl]-
CAS:
1385018-57-4
MF:
C26H27NO2
Structure:
Chemical Name:
24R-Calcipotriol
CAS:
112827-99-3
MF:
C27H40O3
Chemical Name:
Methotrexate IMpurity C
Structure:
Chemical Name:
Paroxetine EP IMpurity G
CAS:
69675-10-1
MF:
C12H14FN
Chemical Name:
Itraconazole impurity C
Structure:
Chemical Name:
1-cyclopropyl-8-ethoxy-6,7-difluoro-4-oxo-1,4-dihydroquinoline-3-carboxylic acid
CAS:
143158-55-8
MF:
C15H13F2NO4
Structure:
Chemical Name:
(1S,3S,4R)-Entecavir
CAS:
1367369-79-6
MF:
C12H15N5O3
Structure:
Chemical Name:
N-[(1R,3r,5S)-9-azabicyclo[3.3.1]non-3-yl]-1-Methyl-1H-indazole-3-carboxaMide hydrochloride
CAS:
141136-01-8
MF:
C17H23ClN4O
Structure:
Chemical Name:
BIRG 616 BS
CAS:
287980-84-1
MF:
C12H10N4O
Structure:
Chemical Name:
3-AMino-4-(2-chlorophenyl)-6-nitro-2(1H)-quinolinone
CAS:
55198-89-5
MF:
C15H10ClN3O3
Structure:
Chemical Name:
3-Dehydroxy-3-oxo-4,5-dihydro OxazepaM
CAS:
19554-95-1
MF:
C15H11ClN2O2
Structure:
Chemical Name:
8-DeMethyl Ivabradine
CAS:
304464-97-9
MF:
C26H34N2O5
Structure:
Chemical Name:
CitalopraM DiMethylaMinobutanone
CAS:
1329745-98-3
MF:
C25H33FN2O2
Structure:
Chemical Name:
DesMethyl Erlotinib Carboxylate Acid
CAS:
882172-60-3
MF:
C21H19N3O5
Chemical Name:
AzithroMycin IMpurity J
Structure:
Chemical Name:
EsMolol Acid SodiuM Salt
CAS:
83356-60-9
MF:
C15H22NNaO4
Structure:
Chemical Name:
Thyroxine Ethyl Ester
CAS:
76353-71-4
MF:
C17H15I4NO4
Structure:
Chemical Name:
(6R,7R)-7-((Z)-2-(2-aMinothiazol-4-yl)-2-(hydroxyiMino)acetaMido)-8-oxo-3-vinyl-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylic acid 5-oxide
CAS:
934986-48-8
MF:
C14H13N5O6S2
Structure:
Chemical Name:
(2S)-1-[(2S)-2-Methyl-3-Methylsulfinylpropanoyl]pyrrolidine-2-carboxylic acid
CAS:
78636-31-4
MF:
C14H22N2O6S2
Structure:
Chemical Name:
Aripiprazole Related CoMpound B
CAS:
1424858-02-5
MF:
C26H32N2O5
Chemical Name:
Mixture of diastereoisoMers of (6S)-6-N-[3-[(6S)-2-aMino-4,5, 6,7-tetrahydro-1,3-benzothiazol-6-yl]-1-ethyl-2-Methylpropyl]- 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diaMine
Chemical Name:
penilloic acids of piperacillin
Structure:
Chemical Name:
2-PyrazinecarboxaMide, 6-nitro-3,4-dihydro-3-oxo-
CAS:
259793-97-0
MF:
C5H4N4O4
Chemical Name:
IMp. C (EP)
Structure:
Chemical Name:
Methyl 3-aMino-2-((2'-carbaMoylbiphenyl-4-yl)MethylaMino)benzoate
CAS:
147404-75-9
MF:
C22H21N3O3
Structure:
Chemical Name:
3-Methyl cefdinir
CAS:
71091-93-5
MF:
C13H13N5O5S2
Chemical Name:
3-Methyl- N-[4-trifluo- roMethyl) phenyl]-4- isoxazole carboxaMide
Structure:
Chemical Name:
2-[[[4-(2,2,2-Trifluoroethoxy)-3-Methyl-1-oxopyridin-2-yl]Methyl]sulfanyl]-1H-benziMidazole
CAS:
163119-30-0
MF:
C16H14F3N3O2S
Structure:
Chemical Name:
(11β,16β)-9-BroMo-11-hydroxy-16-Methyl-17,21-bis(1-oxopropoxy)pregna-1,4-diene-3,20-dione
CAS:
52092-14-5
MF:
C28H37BrO7
Structure:
Chemical Name:
Platycodin D2
CAS:
66663-90-9
MF:
C63H102O33
Structure:
Chemical Name:
Prasugrel Impurity III
CAS:
1391194-50-5
MF:
C20H20FNO3S
Structure:
Chemical Name:
2-(4-(6-((5-((2-chloro-6-Methylphenyl)carbaMoyl)thiazol-2-yl)aMino)-2-MethylpyriMidin-4-yl)piperazin-1-yl)ethyl acetate
CAS:
1245157-85-0
MF:
C24H28ClN7O3S
Structure:
Chemical Name:
Ebastine IMpurity F
CAS:
1429071-63-5
MF:
C32H39NO3
Structure:
Chemical Name:
N-((S)-1-(((R)-1-Hydroxy-3-Methylbutyl)aMino)-1-oxo-3-phenylpropan-2-yl)pyrazine-2-carboxaMide
CAS:
289472-78-2
MF:
C19H24N4O3
Structure:
Chemical Name:
AMoxicillin iMpurity J
CAS:
2088960-43-2
MF:
C32H38N6O10S2
Structure:
Chemical Name:
Azilsartan iMpurity O
CAS:
2171316-29-1
MF:
C23H19N3O4
Chemical Name:
cefoxitin iMpurity C
Structure:
Chemical Name:
3-((3R,4R)-3-((2-chloro-7H-pyrrolo[2,3-d]pyriMidin-4-yl)(Methyl)aMino)-4-Methylpiperidin-1-yl)-3-oxopropanenitrile
CAS:
1616761-00-2
MF:
C16H19ClN6O
Structure:
Chemical Name:
Aprepitant iMpurity
CAS:
96730-04-0
MF:
C13H22NO4P
Structure:
Chemical Name:
Doxofylline iMpurity
CAS:
254760-82-2
MF:
C11H16N4O4
Chemical Name:
forMoterol iMpurity
Structure:
Chemical Name:
LevetiracetaM IMpurity 4
CAS:
1342229-32-6
MF:
C10H19NO4
Structure:
Chemical Name:
cinacalcet iMpurity 4
CAS:
955373-56-5
MF:
C22H20F3N
Structure:
Chemical Name:
(4-Chlorophenyl)[4-(1-Methylethoxy)phenyl]Methanone (Fenofibrate IMpurity)
CAS:
154356-96-4
MF:
C16H15ClO2
Structure:
Chemical Name:
5-Acetyl Rhein
CAS:
875535-35-6
MF:
C17H10O7
Structure:
Chemical Name:
7'-Methyl-2'-propyl-1H,3'H-2,5'-bibenzo[d]iMidazole
CAS:
884330-09-0
MF:
C18H18N4
Structure:
Chemical Name:
5-Des[2-(tert-butylaMino)] BaMbuterol-5-ethanol
CAS:
112935-93-0
MF:
C14H20N2O5
Structure:
Chemical Name:
Deoxy Fesoterodine
CAS:
895137-81-2
MF:
C26H37NO2
Structure:
Chemical Name:
Cyantraniliprole
CAS:
736994-63-1
MF:
C19H14BrClN6O2
Structure:
Chemical Name:
Bisacodyl Related Compound C (20 mg) (4-[(4-Hydroxyphenyl)(pyridin-2-yl)methyl]phenyl acetate)
CAS:
72901-16-7
MF:
C20H17NO3
Chemical Name:
Acyclovir IMpurity J
Chemical Name:
AzithroMycin IMpurity K
Structure:
Chemical Name:
AztreonaM IMpurity F
CAS:
102579-57-7
MF:
C15H21N5O8S2
Chemical Name:
BendaMustine Dideschloroethyl IMpurity
Structure:
Chemical Name:
BroMocriptine IMpurity F
CAS:
82773-21-5
MF:
C32H40BrN5O5
Structure:
Chemical Name:
Cephalexin IMpurity J
MF:
C16H17N3O4S
Structure:
Chemical Name:
Cetirizine IMpurity (4-Chlorobenzophenone)
CAS:
2724877-99-8
MF:
C21H25ClN2O3
Chemical Name:
Dasatinib IMpurity 3
Chemical Name:
Deferasirox IMpurity 2
Structure:
Chemical Name:
Desvenlafaxine (O-DesMethyl Venlafaxine) FuMarate
CAS:
93414-04-1
MF:
C20H29NO6
Structure:
Chemical Name:
EzetiMibe Dehydoxy IMpurity
CAS:
204589-58-2
MF:
C24H21F2NO2
Chemical Name:
Flurbiprofen IMpurity E
Chemical Name:
Levocarnitine IMpurity D
Structure:
Chemical Name:
Montelukast EP IMpurity E
CAS:
1187586-58-8
MF:
C41H46ClNO5S2
Chemical Name:
Prasugrel IMpurity 6
Structure:
Chemical Name:
RebaMipide 2-Chloro IMpurity
CAS:
90098-06-9
MF:
C19H15ClN2O4
Chemical Name:
Ribavirin IMp. F (EP)
Chemical Name:
RocuroniuM BroMide IMpurity 17
Structure:
Chemical Name:
SalMeterol IMpurity D
MF:
C25H37NO4
Chemical Name:
SulbactaM IMpurity A
Structure:
Chemical Name:
Tigecycline Metabolite M6 (9-AniMoMinocycline)
CAS:
149934-19-0
MF:
C23H28N4O7
Structure:
Chemical Name:
VerapaMil IMpurity G
MF:
C27H38N2O4
Structure:
Chemical Name:
EthanediaMide iMpurity D
CAS:
480452-36-6
MF:
C21H30ClN5O5
Structure:
Chemical Name:
N-(4-(2-Methyl-5,6-dihydro-4H-benzo[b]oxazolo[5,4-d]azepine-6-carbonyl)phenyl)-[1,1'-biphenyl]-2-carboxaMide
CAS:
168626-93-5
MF:
C32H25N3O3
Structure:
Chemical Name:
1-(4-chlorophenyl)-7-oxo-6-(4-(2-oxopiperidin-1-yl)phenyl)-4,5,6,7-tetrahydro-1H-pyrazolo[3,4-c]pyridine-3-carboxaMide
MF:
C24H22ClN5O3
Structure:
Chemical Name:
Methyl (4-Methylpiperidin-3-yl)carbaMate
CAS:
1204176-45-3
MF:
C8H16N2O2
Structure:
Chemical Name:
(R)-3-(4-(5-broMo-2-chlorobenzyl)phenoxy)tetrahydrofuran
CAS:
915095-90-8
MF:
C17H16BrClO2
Structure:
Chemical Name:
(2S,3R,4S,5S,6R)-2-(3-((5-(4-fluorophenyl)thiophen-2-yl)Methyl)-4-Methylphenyl)-tetrahydro-6-(hydroxyMethyl)-2-Methoxy-2H-pyran-3,4,5-triol
CAS:
1358581-37-9
MF:
C25H27FO6S
Structure:
Chemical Name:
Levocarnitine iMpurity
CAS:
6490-20-6
MF:
C7H17ClN2O2
Structure:
Chemical Name:
3-Hydroxy-4-Methyl-2(5H)-thiophenone
CAS:
34876-35-2
MF:
C5H6O2S
Structure:
Chemical Name:
(1S,3R,7S,8S,8aR)-1,2,3,7,8,8a-Hexahydro-3,7-diMethyl-8-[2-[(2R,4R)-tetrahydro-4-hydroxy-6-oxo-2H-pyran-2-yl]ethyl]-1-naphthalenyl Ester (2Z)-2-Methyl-2-butenoic Acid
CAS:
1048973-04-1
MF:
C24H34O5
Structure:
Chemical Name:
(6α)-17,21-Dihydroxy-6-Methylpregna-1,4,9(11)-triene-3,20-dione
CAS:
93269-35-3
MF:
C22H28O4
Structure:
Chemical Name:
[N(Z)]-N-(3,5-DiMethyl-2(3H)-thiazolylidene)-4-hydroxy-2-Methyl-2H-1,2-benzothiazine-3-carboxaMide 1,1-Dioxide
CAS:
1262333-25-4
MF:
C15H15N3O4S2
Structure:
Chemical Name:
Quetiapine Impurity E
CAS:
1371638-05-9
MF:
C40H44N6O2S2
Structure:
Chemical Name:
Bendamustine Deschloro Dimer Impurity
CAS:
1391052-61-1
MF:
C32H44N6O7
Structure:
Chemical Name:
Benzenepropanoic acid, β-aMino-α-hydroxy-, Methyl ester, (αR,βR)-
CAS:
157722-44-6
MF:
C10H13NO3
Structure:
Chemical Name:
Benzenebutanoicacid,b-aMino-2,4,5-trifluoro-,Methylester,(bR)-
CAS:
881995-69-3
MF:
C11H12F3NO2
Chemical Name:
Avanafil iMpurity 2
Structure:
Chemical Name:
Bisoprolol IMpurity
CAS:
2226263-67-6
MF:
C18H31NO4