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Heterocyclic compound

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Heterocyclic compounds are a class of organic compounds with cyclic structure. The ring-constituting atoms in the molecule, in addition to carbon, also include one or more nitrogen, sulfur, oxygen and other atoms. Those containing one ring are called single-heterocyclic compounds, such as furan, thiazole, and pyridine. Those containing two or more rings are called fused heterocyclic compounds such as quinoline and purine. The most common and most stable are five- or six-membered heterocyclic ring. Simple heterocyclic ring is capable of merging with benzene or another heterocyclic ring to form a bicyclic, tricyclic or more complex ring system. Some kinds of heterocyclic rings have features of aromatic compounds, such as being easy to participate into substitution reaction, difficult to have addition reaction and being stable to oxidant. Heterocyclic compounds are widely found in nature, such as nucleic acids, most kinds of vitamins, chlorophyll, heme, most kinds of alkaloids, pigments and so on. A fraction of the heterocyclic compounds have aromatic characteristics, such as plants coumarone, jasmonate and animals civetone. There are many synthetic pesticides that belong to such compounds such as herbicides atrazine, amitrole, CMPT, insecticide fluorine propargite, quinoline parathion, thioquinox and so on. Simple heterocyclic compound is an important raw material of organic chemical industry.

The cyclic compounds with atoms constituting the ring system, in addition to carbon atom, also containing O, S, and N heteroatom are collectively referred to as heterocyclic compounds. According to this definition, the cyclic dicarboxylic anhydride, the cyclic imide, lactones, lactides, cyclic anhydrides, lactams, and cyclic ethers, strictly speaking, also belong to heterocyclic compounds. However, due to the nature of these compounds are similar with aliphatic compound, and can easily undergo either the cyclization of the open-chain compounds or ring open reaction to be transformed into chain compounds, thus being generally attributed to the aliphatic chemistry for discussion. Therefore, heterocyclic compounds generally refer specifically to those heterocyclic compounds with relatively stable ring system but different levels of aromatic properties, namely aromatic heterocyclic compound.

The organic heterocyclic compounds belong to a large class in the three large categories of organic compounds, open chain, carbocyclic and heterocyclic organic compounds. It contains various kinds and has a large number accounting for about one-third of all known organic compounds and is also widespread in the biosphere, having close relation with the biological growth, development, reproduction, and genetic variation and so on. Common heterocyclic compounds include furan, thiophene, pyrrole, pyridine, quinoline, carbazole and so on.

These kinds of heterocyclic compounds are widely used in organic synthesis or as pharmaceuticals, pesticides, solvents and so on. They are colorless liquids with special smell or crystallization and have specific gravity being less than or close to water. They are toxic and can be soluble in some organic solvents and slightly soluble in water. In case of fire, heat, oxidants and strong acids, it can cause fire or explosion with simultaneous deposition of toxic sulfur dioxide or nitrogen oxide gas. Furan, when being exposed to the air, is capable of forming peroxides with causing an explosion during distillation. In the management of dangerous goods, according to the risk grades of fire, explosion, toxicity risk, they were classified as flammable liquids, flammable solids and organic toxic chemicals; when used in the reservoir, the first two comply danger of the A and B class while the latter one is based on class C fire danger for conducting fire management. In case of fire, we can use foam, dry powder, water mist, 1211 and carbon dioxide for fire extinguishing agents.

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Structure:
Chemical Name:
5-Chlorothiophene-2-sulfonamide
CAS:
53595-66-7
MF:
C4H4ClNO2S2
Structure:
Chemical Name:
2,5-Dichlorothiophene
CAS:
3172-52-9
MF:
C4H2Cl2S
Structure:
Chemical Name:
6-Aminoquinoxaline
CAS:
6298-37-9
MF:
C8H7N3
Structure:
Chemical Name:
4,4'-Dimethyl-2,2'-bipyridyl
CAS:
1134-35-6
MF:
C12H12N2
Structure:
Chemical Name:
Tetrabromothiophene
CAS:
3958-03-0
MF:
C4Br4S
Structure:
Chemical Name:
4-Bromothiophene-2-carboxaldehyde
CAS:
18791-75-8
MF:
C5H3BrOS
Structure:
Chemical Name:
5-Bromoquinoline
CAS:
4964-71-0
MF:
C9H6BrN
Structure:
Chemical Name:
5-Chloro-7-azaindole
CAS:
866546-07-8
MF:
C7H5ClN2
Structure:
Chemical Name:
4-Chloronicotinic acid
CAS:
10177-29-4
MF:
C6H4ClNO2
Structure:
Chemical Name:
3-Bromoquinoline
CAS:
5332-24-1
MF:
C9H6BrN
Structure:
Chemical Name:
2-Chloro-3-pyridinecarboxaldehyde
CAS:
36404-88-3
MF:
C6H4ClNO
Structure:
Chemical Name:
6,7-Dimethoxy-3,4-dihydroquinazoline-4-one
CAS:
13794-72-4
MF:
C10H10N2O3
Structure:
Chemical Name:
3-Bromothiophene-2-carbaldehyde
CAS:
930-96-1
MF:
C5H3BrOS
Structure:
Chemical Name:
4-Chloro-6-fluoroquinoline
CAS:
391-77-5
MF:
C9H5ClFN
Structure:
Chemical Name:
3-Bromoisonicotinic acid
CAS:
13959-02-9
MF:
C6H4BrNO2
Structure:
Chemical Name:
4-Chloro-7-(trifluoromethyl)quinoline
CAS:
346-55-4
MF:
C10H5ClF3N
Structure:
Chemical Name:
6-Methoxyquinaldine
CAS:
1078-28-0
MF:
C11H11NO
Structure:
Chemical Name:
2-Chloro-4-pyridinecarboxylic acid
CAS:
6313-54-8
MF:
C6H4ClNO2
Structure:
Chemical Name:
4-Hydroxy-2-methylindole
CAS:
35320-67-3
MF:
C9H9NO
Structure:
Chemical Name:
3-Acetylthiophene
CAS:
1468-83-3
MF:
C6H6OS
Structure:
Chemical Name:
2-Thiopheneacetonitrile
CAS:
20893-30-5
MF:
C6H5NS
Structure:
Chemical Name:
3-Thienylmethanol
CAS:
71637-34-8
MF:
C5H6OS
Structure:
Chemical Name:
2,5-Dichloroisonicotinic acid
CAS:
88912-26-9
MF:
C6H3Cl2NO2
Structure:
Chemical Name:
5-Nitroquinoline
CAS:
607-34-1
MF:
C9H6N2O2
Structure:
Chemical Name:
Pyridinium chlorochromate
CAS:
26299-14-9
MF:
C5H6ClCrNO3
Structure:
Chemical Name:
2-Bromo-5-methylthiophene
CAS:
765-58-2
MF:
C5H5BrS
Structure:
Chemical Name:
2-Fluoronicotinic acid
CAS:
393-55-5
MF:
C6H4FNO2
Structure:
Chemical Name:
4-Hydroxy-6,7-dimethoxyqunioline
CAS:
13425-93-9
MF:
C11H11NO3
Structure:
Chemical Name:
5,7-Dichloro-8-hydroxyquinaldine
CAS:
72-80-0
MF:
C10H7Cl2NO
Structure:
Chemical Name:
8-Quinolinecarboxylic acid
CAS:
86-59-9
MF:
C10H7NO2
Structure:
Chemical Name:
6-BROMO-4-HYDROXYQUINOLINE
CAS:
145369-94-4
MF:
C9H6BrNO
Structure:
Chemical Name:
6-Bromopicolinic acid
CAS:
21190-87-4
MF:
C6H4BrNO2
Structure:
Chemical Name:
1-Methylpiperidin-4-amine
CAS:
41838-46-4
MF:
C6H14N2
Structure:
Chemical Name:
METHYL QUINOLINE-6-CARBOXYLATE
CAS:
38896-30-9
MF:
C11H9NO2
Structure:
Chemical Name:
4-Quinolinecarboxaldehyde
CAS:
4363-93-3
MF:
C10H7NO
Structure:
Chemical Name:
Thiophene-2-ethylamine
CAS:
30433-91-1
MF:
C6H9NS
Structure:
Chemical Name:
7-Methoxy-4-quinolinol
CAS:
82121-05-9
MF:
C10H9NO2
Structure:
Chemical Name:
3,4-Ethylenedioxythiophene
CAS:
126213-50-1
MF:
C6H6O2S
Structure:
Chemical Name:
2-Hydroxy-5-pyridinecarboxylic acid
CAS:
5006-66-6
MF:
C6H5NO3
Structure:
Chemical Name:
6,7-Dihydro-5H-quinolin-8-one
CAS:
56826-69-8
MF:
C9H9NO
Structure:
Chemical Name:
1,2,3,4-TETRAHYDROISOQUINOLINE
CAS:
91-21-4
MF:
C9H11N
Structure:
Chemical Name:
5-Hydroxyquinoline
CAS:
578-67-6
MF:
C9H7NO
Structure:
Chemical Name:
6-HYDROXYQUINOLINE
CAS:
19315-93-6
MF:
C9H7NO2
Structure:
Chemical Name:
8-FLUORO-4-HYDROXYQUINOLINE
CAS:
63010-71-9
MF:
C9H6FNO
Structure:
Chemical Name:
2,5-Dibromo-3-hexylthiophene
CAS:
116971-11-0
MF:
C10H14Br2S
Structure:
Chemical Name:
2,2'-Bipyridine-4,4'-dicarboxylic acid
CAS:
6813-38-3
MF:
C12H8N2O4
Structure:
Chemical Name:
4-Hydroxyquinazoline
CAS:
491-36-1
MF:
C8H6N2O
Structure:
Chemical Name:
8-Bromoisoquinoline
CAS:
63927-22-0
MF:
C9H6BrN
Structure:
Chemical Name:
5-Amino-8-quinolinol dihydrochloride
CAS:
21302-43-2
MF:
C9H10Cl2N2O
Structure:
Chemical Name:
2-Amino-3,5-dibromopyrazine
CAS:
24241-18-7
MF:
C4H3Br2N3
Structure:
Chemical Name:
5,6-Dichloronicotinic acid
CAS:
41667-95-2
MF:
C6H3Cl2NO2
Structure:
Chemical Name:
6-Chloro-4-hydroxy-2-methyl-2H-thieno[2,3-e]-1,2-thiazine-3-carboxylic acid methyl ester 1,1-dioxide
CAS:
70415-50-8
MF:
C9H8ClNO5S2
Structure:
Chemical Name:
3-Quinolinecarboxylic acid
CAS:
6480-68-8
MF:
C10H7NO2
Structure:
Chemical Name:
8-Aminoquinaldine
CAS:
18978-78-4
MF:
C10H10N2
Structure:
Chemical Name:
3,4-Dihydro-7-hydroxy-2(1H)-quinolinone
CAS:
22246-18-0
MF:
C9H9NO2
Structure:
Chemical Name:
2-HYDRAZINOQUINOLINE
CAS:
15793-77-8
MF:
C9H9N3
Structure:
Chemical Name:
2,4-Quinolinediol
CAS:
86-95-3
MF:
C9H7NO2
Structure:
Chemical Name:
2-Bromopyridine-5-carbaldehyde
CAS:
149806-06-4
MF:
C6H4BrNO
Structure:
Chemical Name:
2-Chloroquinoline
CAS:
612-62-4
MF:
C9H6ClN
Structure:
Chemical Name:
2-Bromoquinoline
CAS:
2005-43-8
MF:
C9H6BrN
Structure:
Chemical Name:
3-Methylquinoline
CAS:
612-58-8
MF:
C10H9N
Structure:
Chemical Name:
5-Fluoronicotinic acid
CAS:
402-66-4
MF:
C6H4FNO2
Structure:
Chemical Name:
2-Chloro-6-methoxypyridine
CAS:
17228-64-7
MF:
C6H6ClNO
Structure:
Chemical Name:
2-Quinolinol
CAS:
59-31-4
MF:
C9H7NO
Structure:
Chemical Name:
3,4-DIHYDROQUINOLIN-2(1H)-ONE
CAS:
553-03-7
MF:
C9H9NO
Structure:
Chemical Name:
2,5-PYRIDINEDICARBOXYLIC ACID
CAS:
100-26-5
MF:
C7H5NO4
Structure:
Chemical Name:
4-Chloro-N-methylpicolinamide
CAS:
220000-87-3
MF:
C7H7ClN2O
Structure:
Chemical Name:
3-Thiophenezoic acid
CAS:
88-13-1
MF:
C5H4O2S
Structure:
Chemical Name:
2,5-DIBROMO-3-DECYLTHIOPHENE
CAS:
158956-23-1
MF:
C14H22Br2S
Structure:
Chemical Name:
7-Hydroxyisoquinoline
CAS:
7651-83-4
MF:
C9H7NO
Structure:
Chemical Name:
2,6-Pyridinedimethanol
CAS:
1195-59-1
MF:
C7H9NO2
Structure:
Chemical Name:
2-(Chloromethyl)quinoline hydrochloride
CAS:
3747-74-8
MF:
C10H9Cl2N
Structure:
Chemical Name:
Ethyl picolinate
CAS:
2524-52-9
MF:
C8H9NO2
Structure:
Chemical Name:
2-CHLOROQUINOLINE-4-CARBOXYLIC ACID
CAS:
5467-57-2
MF:
C10H6ClNO2
Structure:
Chemical Name:
4-AMINO-2-METHYLQUINOLINE
CAS:
6628-04-2
MF:
C10H10N2
Structure:
Chemical Name:
5-Methylthiophene-2-carboxaldehyde
CAS:
13679-70-4
MF:
C6H6OS
Structure:
Chemical Name:
2-Bromo-5-hydroxypyrazine
CAS:
374063-92-0
MF:
C4H3BrN2O
Structure:
Chemical Name:
5-Bromo-2-thiophenecarboxylic acid
CAS:
7311-63-9
MF:
C5H3BrO2S
Structure:
Chemical Name:
3-Quinolineboronic acid
CAS:
191162-39-7
MF:
C9H8BNO2
Structure:
Chemical Name:
DBU
CAS:
6674-22-2
MF:
C9H16N2
Structure:
Chemical Name:
6-Methoxyisoquinoline
CAS:
52986-70-6
MF:
C10H9NO
Structure:
Chemical Name:
5,6,7,8-Tetrahydroquinoline
CAS:
10500-57-9
MF:
C9H11N
Structure:
Chemical Name:
Methyl 6-aminonicotinate
CAS:
36052-24-1
MF:
C7H8N2O2
Structure:
Chemical Name:
2-Thiopheneethanol
CAS:
5402-55-1
MF:
C6H8OS
Structure:
Chemical Name:
Cyclopenta[b]pyridine
CAS:
533-37-9
MF:
C8H9N
Structure:
Chemical Name:
5-Bromo-7-azaindole
CAS:
183208-35-7
MF:
C7H5BrN2
Structure:
Chemical Name:
4-Chloro-3-nitroquinoline
CAS:
39061-97-7
MF:
C9H5ClN2O2
Structure:
Chemical Name:
8-Aminoquinoline
CAS:
578-66-5
MF:
C9H8N2
Structure:
Chemical Name:
8-Hydroxyquinaldine
CAS:
826-81-3
MF:
C10H9NO
Structure:
Chemical Name:
3,4-Pyridinedicarboxylic acid
CAS:
490-11-9
MF:
C7H5NO4
Structure:
Chemical Name:
2-Chloro-3-methylthiophene
CAS:
14345-97-2
MF:
C5H5ClS
Structure:
Chemical Name:
2,3-DIHYDROXYQUINOXALINE
CAS:
15804-19-0
MF:
C8H6N2O2
Structure:
Chemical Name:
XANTHURENIC ACID
CAS:
59-00-7
MF:
C10H7NO4
Structure:
Chemical Name:
3-Bromothiophene
CAS:
872-31-1
MF:
C4H3BrS
Structure:
Chemical Name:
2-(5-BroMo-2-Methylbenzyl)-5-(4-fluorophenyl)thiophene
CAS:
1030825-20-7
MF:
C18H14BrFS
Structure:
Chemical Name:
8-Hydroxyquinoline sulfate
CAS:
134-31-6
MF:
2C9H7NO.H2O4S
Structure:
Chemical Name:
1,2,3,4-Tetrahydroquinoline
CAS:
635-46-1
MF:
C9H11N
Structure:
Chemical Name:
2,4-Dichloro-6,7-dimethoxyquinazoline
CAS:
27631-29-4
MF:
C10H8Cl2N2O2
Structure:
Chemical Name:
3,4-Dimethoxythiophene
CAS:
51792-34-8
MF:
C6H8O2S
Structure:
Chemical Name:
5-Aminoquinoline
CAS:
611-34-7
MF:
C9H8N2