Esters Aromatic acids fatty acid Fatty alcohols Boric acid Cyanide / nitrile Aromatic ketones Aromatic aldehydes Halogenated aliphatic hydrocarbons aliphatic ketones Amide Ethers Aromatics Aromatic alcohol Phosphine ligand Phenols Thiol / thiol Silane Acyl halide Sulfonates / Sulfinates salts Cyanate ester / isocyanate Nitro compounds Imide Olefin (cyclic and acyclic) The polycyclic compound Hydrazine Amine salt (ammonium salt) Aliphatic aldehydes Bicyclic compound Oxime Tricyclic compound Alkanes Sulfonyl halide Phosphonate / phosphonate Phosphorus halide Alkyne Carboxylic anhydride Urea Phosphorus-containing compound Siloxane Azo, diazo compound Ionic Liquids Thiocyanate / isothiocyanate Borate Sulfonates / Sulfinates Selenium compounds Guanidine salt Borane Thiourea Thiolate tetrafluoroborate Thiol ester Polycyclic compound Crown ether Sulfone, sulfoxide compound Hydrazone Imide, amidine Polyamines Tosylate Epoxide Azide Hydroxylamine Cyclodextrin
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Organic reagents

Esters Aromatic acids fatty acid Fatty alcohols Boric acid Cyanide / nitrile Aromatic ketones Aromatic aldehydes Halogenated aliphatic hydrocarbons aliphatic ketones Amide Ethers Aromatics Aromatic alcohol Phosphine ligand Phenols Thiol / thiol Silane Acyl halide Sulfonates / Sulfinates salts Cyanate ester / isocyanate Nitro compounds Imide Olefin (cyclic and acyclic) The polycyclic compound Hydrazine Amine salt (ammonium salt) Aliphatic aldehydes Bicyclic compound Oxime Tricyclic compound Alkanes Sulfonyl halide Phosphonate / phosphonate Phosphorus halide Alkyne Carboxylic anhydride Urea Phosphorus-containing compound Siloxane Azo, diazo compound Ionic Liquids Thiocyanate / isothiocyanate Borate Sulfonates / Sulfinates Selenium compounds Guanidine salt Borane Thiourea Thiolate tetrafluoroborate Thiol ester Polycyclic compound Crown ether Sulfone, sulfoxide compound Hydrazone Imide, amidine Polyamines Tosylate Epoxide Azide Hydroxylamine Cyclodextrin
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From early AD to mid-19 century, people mainly use the natural organic substance (such as animal and plant extracts) for qualitative analysis or quantitative analysis. From the second half of the 19th century to the 1920s, it had begun to appear of artificially synthetic organic reagent such as using potassium acetate xanthan for test of nickel, copper, and molybdenum; using morin for test of aluminum; using diazo coupling reaction for the detection of Nitrite; using α-β-nitroso naphthol for detection of cobalt; using dimethyglyoxime for nickel test.

After the proposal of the special-effects group in the 1930s and the proposal of theoretical analysis of functional groups theory in 1950s, people had carried out large-scale screen of organic reagents in search of special-effects analysis groups for different ions and had successfully synthesized a lot of agents of practical value (such as copper reagents, new copper agent, cadmium reagents, beryllium reagent, thorium reagents, etc.). Before the 1950s, the complex compound, in analytic chemistry, is mainly used in the aspects of the precipitation reaction of a binary chelate for the qualitative detection, precipitate isolation and gravimetric separation and other aspects. In the early 1950s and 1960, it is mainly in the form of complexometric titration. From the beginning of the late 1960s, the main focus has been moved to the photometric analysis. Meanwhile, it has been also developed of chelate organic solvent extraction.

8-hydroxy quinoline, hydrazones, oximes, hydroxamic acids, polyphenols, 1, 10-phenanthroline, phosphorus-oxygen extractant, β- diketones, triphenylmethane acid dye, xanthene dyes and azo dyes and other agents has all been widely studied and applied. On the other hand, the structural theoretical research (such as electronic effects, spatial effects and substituent effects) of the organic reagent can further facilitate the development of new-type organic reagents such as heterocyclic azo reagent. During this period, it has been also developed of monoazo chromotropic acid-type and disazo chromotropic acid-type reagent. During the mid-1970s, the chelating resin and adsorbents have achieved rapid development. Since the 1980s, Chinese researchers of analytical chemistry have made progress in the field of the synthesis and application of asymmetric disazo chromotropic acid.

Organic chemical reagents have wide application in analytic chemistry and are mainly used in solvents, precipitation agents, complexing agents, indicator, coloring reagent and surface active agent, etc. In order to adapt to a variety of analytical needs, sometimes it is required to purify certain reagents. For example, liquid organic reagent is often purified by distillation while solid substance is often purified through crystallization and sublimation. Substance having a high vapor pressure, namely having low purification boiling point and undergoing no decomposition under boiling temperature commonly applied atmospheric distillation; for less volatile and water-insoluble substance, namely having high purification point or undergoing decomposition under boiling temperature, we can apply vacuum distillation or steam distillation for purification of it.

Distillation is a commonly used method for laboratory purification of organic reagent. Conventional distillation apparatus generally comprises distiller, condenser and receiver, three parts with auxiliary section also containing heater, a thermometer, a wetted tube and cork.

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Structure:
Chemical Name:
TRIFLUOROACETYL TRIFLATE
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68602-57-3
MF:
C3F6O4S
Structure:
Chemical Name:
N-Methyl-N-vinylacetamide
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3195-78-6
MF:
C5H9NO
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Chemical Name:
1-METHYLPYRENE
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2381-21-7
MF:
C17H12
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Chemical Name:
Fluorene-9-acetic acid
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6284-80-6
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C15H12O2
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Chemical Name:
1,5-HEXADIENE DIEPOXIDE
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1888-89-7
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C6H10O2
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Chemical Name:
POTASSIUM SELENATE
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7790-59-2
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H3KO4Se
Structure:
Chemical Name:
3-HEXYNE
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928-49-4
MF:
C6H10
Structure:
Chemical Name:
5-CHLORO-2-METHYLPHENYL ISOCYANATE
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40411-27-6
MF:
C8H6ClNO
Structure:
Chemical Name:
PROPIONALDEHYDE 2,4-DINITROPHENYLHYDRAZONE
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725-00-8
MF:
C9H10N4O4
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Chemical Name:
HEXACHLORODISILANE
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13465-77-5
MF:
Cl6Si2
Structure:
Chemical Name:
TRI-N-PROPYLCHLOROSILANE
CAS:
995-25-5
MF:
C9H21ClSi
Structure:
Chemical Name:
4-TERT-BUTYLPHENYLACETIC ACID
CAS:
32857-63-9
MF:
C12H16O2
Structure:
Chemical Name:
3-PHENYL-1,1,1-TRIFLUOROPROPAN-2-ONE
CAS:
350-92-5
MF:
C9H7F3O
Structure:
Chemical Name:
FENAMIPHOS SULFOXIDE
CAS:
31972-43-7
MF:
C13H22NO4PS
Structure:
Chemical Name:
5-(2-METHOXYPHENYL)-1,3,4-OXADIAZOLE-2-THIOL
CAS:
69844-25-3
MF:
C9H8N2O2S
Structure:
Chemical Name:
1-NAPHTHYL PROPIONATE
CAS:
3121-71-9
MF:
C13H12O2
Structure:
Chemical Name:
1-CYCLOHEXYL-3-(2-MORPHOLINOETHYL)THIOUREA
CAS:
21545-54-0
MF:
C13H25N3OS
Structure:
Chemical Name:
2-Iodo-4-methoxy-1-nitrobenzene
CAS:
214279-40-0
MF:
C7H6INO3
Structure:
Chemical Name:
6-O-(TRIISOPROPYLSILYL)-D-GLUCAL
CAS:
137915-37-8
MF:
C15H30O4Si
Structure:
Chemical Name:
1H,1H,7H-DODECAFLUORO-1-HEPTANOL
CAS:
335-99-9
MF:
C7H4F12O
Structure:
Chemical Name:
DL-2-Methylbutyryl chloride
CAS:
57526-28-0
MF:
C5H9ClO
Structure:
Chemical Name:
(4-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE
CAS:
2767-70-6
MF:
C25H21BrNO2P
Structure:
Chemical Name:
NAPHTHOL YELLOW S
CAS:
846-70-8
MF:
C10H4N2Na2O8S
Structure:
Chemical Name:
3-CHLORO-2-METHYLBENZONITRILE
CAS:
54454-12-5
MF:
C8H6ClN
Structure:
Chemical Name:
4-N-HEXYLOXYBENZALDEHYDE
CAS:
5736-94-7
MF:
C13H18O2
Structure:
Chemical Name:
2,6-DIMETHOXYTOLUENE
CAS:
5673-07-4
MF:
C9H12O2
Structure:
Chemical Name:
2-(4-METHOXYPHENYL)HYDRAZINESULFONIC ACID SODIUM SALT MONOHYDRATE
CAS:
5446-07-1
MF:
C7H9N2NaO4S
Structure:
Chemical Name:
DIMETHYL CIS-1,2-CYCLOPROPANEDICARBOXYLATE
CAS:
826-34-6
MF:
C7H10O4
Structure:
Chemical Name:
3-METHYLENE-2-NORBORNANONE
CAS:
5597-27-3
MF:
C8H10O
Structure:
Chemical Name:
2,5-Dibromohexane
CAS:
24774-58-1
MF:
C6H12Br2
Structure:
Chemical Name:
PHENOXATHIIN-4-BORONIC ACID
CAS:
100124-07-0
MF:
C12H9BO3S
Structure:
Chemical Name:
GLYCIDYL ISOPROPYL ETHER
CAS:
4016-14-2
MF:
C6H12O2
Structure:
Chemical Name:
TETRAMETHYLAMMONIUM HEXAFLUOROPHOSPHATE
CAS:
558-32-7
MF:
C4H12F6NP
Structure:
Chemical Name:
CROTONALDEHYDE (DNPH DERIVATIVE)
CAS:
1527-96-4
MF:
C10H10N4O4
Structure:
Chemical Name:
3,5-DICHLORO-2-HYDROXYBENZENESULFONYL CHLORIDE
CAS:
23378-88-3
MF:
C6H3Cl3O3S
Structure:
Chemical Name:
2,3-DIMETHYL-6-NITROANILINE
CAS:
59146-96-2
MF:
C8H10N2O2
Structure:
Chemical Name:
3-FLUORO-4-HYDROXYPHENYLACETIC ACID
CAS:
458-09-3
MF:
C8H7FO3
Structure:
Chemical Name:
3-Methylcyclopentanone
CAS:
1757-42-2
MF:
C6H10O
Structure:
Chemical Name:
ETHYL TRANS-2-DECENOATE
CAS:
7367-88-6
MF:
C12H22O2
Structure:
Chemical Name:
CYCLOHEXYLTRIMETHOXYSILANE
CAS:
17865-54-2
MF:
C9H20O3Si
Structure:
Chemical Name:
DIMETHYL PIMELIMIDATE DIHYDROCHLORIDE
CAS:
58537-94-3
MF:
C9H19ClN2O2
Structure:
Chemical Name:
CI 52000
CAS:
78338-22-4
MF:
C14H13N3O2S
Structure:
Chemical Name:
Bromonitromethane
CAS:
563-70-2
MF:
CH2BrNO2
Structure:
Chemical Name:
HYDROXYPROPYL-GAMMA-CYCLODEXTRIN
CAS:
99241-25-5
MF:
C72H128O48
Structure:
Chemical Name:
1,1,1,3,3,3-HEXAFLUOROISOPROPYL METHACRYLATE
CAS:
3063-94-3
MF:
C7H6F6O2
Structure:
Chemical Name:
TRANS-4-DIMETHYLAMINOCINNAMONITRILE
CAS:
32444-63-6
MF:
C11H12N2
Structure:
Chemical Name:
4-PHENOXYPHENYL ISOCYANATE
CAS:
59377-19-4
MF:
C13H9NO2
Structure:
Chemical Name:
Octyl cyanoacetate
CAS:
15666-97-4
MF:
C11H19NO2
Structure:
Chemical Name:
Tetraethylammonium hydrogensulfate
CAS:
16873-13-5
MF:
C8H21NO4S
Structure:
Chemical Name:
2-NAPHTHYL MYRISTATE
CAS:
7262-80-8
MF:
C24H34O2
Structure:
Chemical Name:
4-METHOXYBENZYL ISOTHIOCYANATE
CAS:
3694-57-3
MF:
C9H9NOS
Structure:
Chemical Name:
NAPHTHOL AS-MX
CAS:
92-75-1
MF:
C19H17NO2
Structure:
Chemical Name:
Thymolphthalein Complexone
CAS:
1913-93-5
MF:
C38H44N2O12
Structure:
Chemical Name:
BORIC ACID TRIOCTADECYL ESTER
CAS:
5337-41-7
MF:
C54H111BO3
Structure:
Chemical Name:
9-ETHYNYL-9-FLUORENOL
CAS:
13461-74-0
MF:
C15H10O
Structure:
Chemical Name:
Didodecylamine
CAS:
3007-31-6
MF:
C24H51N
Structure:
Chemical Name:
1-Cyano-1-cyclopropanecarboxylic acid
CAS:
6914-79-0
MF:
C5H5NO2
Structure:
Chemical Name:
3-CYANOPHENYL ISOTHIOCYANATE
CAS:
3125-78-8
MF:
C8H4N2S
Structure:
Chemical Name:
2-(2-DODECYLOXYETHOXY)ETHANOL
CAS:
3055-93-4
MF:
C16H34O3
Structure:
Chemical Name:
2-BUTENE-1,4-DIOL
CAS:
821-11-4
MF:
C4H8O2
Structure:
Chemical Name:
4-Nitrophenyl formate
CAS:
1865-01-6
MF:
C7H5NO4
Structure:
Chemical Name:
4-NITROPHENYL TRIFLUOROMETHANESULFONATE
CAS:
17763-80-3
MF:
C7H4F3NO5S
Structure:
Chemical Name:
2-CHLORO-6-METHYLBENZALDEHYDE
CAS:
1194-64-5
MF:
C8H7ClO
Structure:
Chemical Name:
N-TRIDECYLBENZENE
CAS:
123-02-4
MF:
C19H32
Structure:
Chemical Name:
2,4-HEXADIYNE-1,6-DIOL
CAS:
3031-68-3
MF:
C6H6O2
Structure:
Chemical Name:
4-CARBOXYBENZENESULFONYL AZIDE
CAS:
17202-49-2
MF:
C7H5N3O4S
Structure:
Chemical Name:
2-BROMOHEXANE
CAS:
3377-86-4
MF:
C6H13Br
Structure:
Chemical Name:
BORON TRIFLUORIDE, N-PROPANOL REAGENT 15
CAS:
762-48-1
MF:
C3H7BF3O
Structure:
Chemical Name:
3-HEXADECANONE
CAS:
18787-64-9
MF:
C16H32O
Structure:
Chemical Name:
1-HEPTANESULFONIC ACID SODIUM SALT MONOHYDRATE
CAS:
207300-90-1
MF:
C7H17NaO4S
Structure:
Chemical Name:
6-(1,4-DIAZEPAN-1-YL)NICOTINONITRILE
CAS:
683274-59-1
MF:
C11H14N4
Structure:
Chemical Name:
4-Amino-3,5-diiodobenzoic acid
CAS:
2122-61-4
MF:
C7H5I2NO2
Structure:
Chemical Name:
DIETHYL (CHLOROMETHYL)PHOSPHONATE
CAS:
3167-63-3
MF:
C5H12ClO3P
Structure:
Chemical Name:
(R)-(+)-TolBINAP
CAS:
99646-28-3
MF:
C48H40P2
Structure:
Chemical Name:
NONENYLSUCCINIC ANHYDRIDE
CAS:
28928-97-4
MF:
C13H20O3
Structure:
Chemical Name:
SODIUM XYLENESULFONATE
CAS:
30587-85-0
MF:
C8H9NaO3S
Structure:
Chemical Name:
METHOXY-BIS(DIMETHYLAMINO)METHANE
CAS:
1186-70-5
MF:
C6H16N2O
Structure:
Chemical Name:
1-CYCLOPENTENYLACETONITRILE
CAS:
22734-04-9
MF:
C7H9N
Structure:
Chemical Name:
DIBROMOACETONITRILE
CAS:
3252-43-5
MF:
C2HBr2N
Structure:
Chemical Name:
1-Propanesulfonic acid
CAS:
5284-66-2
MF:
C3H8O3S
Structure:
Chemical Name:
(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE
CAS:
99438-28-5
MF:
C21H37BO
Structure:
Chemical Name:
ARACHIDIC ANHYDRIDE
CAS:
55726-22-2
MF:
C40H78O3
Structure:
Chemical Name:
4-(Trifluoromethylthio)benzyl alcohol
CAS:
56456-52-1
MF:
C8H7F3OS
Structure:
Chemical Name:
3-(N-Styrylmethyl-2-aminoethylamino)-propyltrimethoxysilane hydrochloride
CAS:
34937-00-3
MF:
C17H31ClN2O3Si
Structure:
Chemical Name:
Sodium 1-hexanesulfonate monohydrate
CAS:
207300-91-2
MF:
C6H17NaO4S
Structure:
Chemical Name:
S-ETHYL TRIFLUOROTHIOACETATE
CAS:
383-64-2
MF:
C4H5F3OS
Structure:
Chemical Name:
DIPHENYLENEIODONIUM CHLORIDE
CAS:
4673-26-1
MF:
C12H8ClI
Structure:
Chemical Name:
Diethyl amino methyl triethoxy silane
CAS:
15180-47-9
MF:
C11H27NO3Si
Structure:
Chemical Name:
VINYL BENZOATE
CAS:
769-78-8
MF:
C9H8O2
Structure:
Chemical Name:
2-(4-HYDROXYPHENYL)PROPIONIC ACID
CAS:
938-96-5
MF:
C9H10O3
Structure:
Chemical Name:
(Chloromethyl)trichlorosilane
CAS:
1558-25-4
MF:
CH2Cl4Si
Structure:
Chemical Name:
beta-Pinene
CAS:
127-91-3
MF:
C10H16
Structure:
Chemical Name:
2,3,4,5,6-PENTAFLUOROANISOLE
CAS:
389-40-2
MF:
C7H3F5O
Structure:
Chemical Name:
N,N'-DIBENZOYLHYDRAZINE
CAS:
787-84-8
MF:
C14H12N2O2
Structure:
Chemical Name:
BIS(4-HYDROXY-3-METHYLPHENYL) SULFIDE
CAS:
24197-34-0
MF:
C14H14O2S
Structure:
Chemical Name:
1,4-DIHYDRONAPHTHALENE
CAS:
612-17-9
MF:
C10H10
Structure:
Chemical Name:
N-NONADECANOIC ACID ETHYL ESTER
CAS:
18281-04-4
MF:
C21H42O2
Structure:
Chemical Name:
MARGAROYL CHLORIDE
CAS:
40480-10-2
MF:
C17H33ClO
Structure:
Chemical Name:
(Dichloromethylene)dimethylammonium chloride
CAS:
33842-02-3
MF:
C3H6Cl2N.Cl
Structure:
Chemical Name:
3,5-DI-TERT-BUTYLTOLUENE
CAS:
15181-11-0
MF:
C15H24