Synthetic fragrances
Synthetic fragrances is also known as artificially synthetic fragrance. It is a mimic of the natural flavors manufactured using science and technology by human beings. It refers to a “single-one” spice manufactured or prepared through chemical or biological pathways using different raw materials. Currently, there are already 5000 kinds of Synthetic fragrances in the world with 400 kinds of them belonging to commonly used products. Synthetic fragrances industry has become an important part of fine organic chemical industry.
Synthetic fragrances, according to their chemical structure or functional groups, can be divided into hydrocarbons, alcohols, acids, esters, lactones, aldehydes, ketones, phenols, ethers, acetals, ketals, shiff base, nitrile, macrocyclic, polycyclic, heterocyclic (pyrazine, pyridine, furan furosemide thiazole, etc.), sulfides, halides and so on.
The GB2760 in China allows the application of more than 257 kinds of Synthetic fragrances in the food flavors directories. The commonly used Synthetic fragrances in the beverage can be divided into esters and non-esters, two kinds.
(1) Synthetic esters spices: the esters of organic acids and alcohols, due to undergoing alkali saponification, generally have poor alkali resistance except the third class terpene alcohol esters (terpinyl acetate, linalyl acetate). The esters spices are generally prepared through the esterification of organic acids and alcohols. Among the esters spices listed in Table 1-4-21, acetate esters occupy the majority, up to 12 species. From the component of the alcohol, the number of alcohol ester is 11; the number of iso-amyl alcohol esters is 7; the number of methyl ester is 5. These kinds of esters are all difficultly soluble or almost insoluble in water, but being easily soluble in alcohol and ether. Owing to the highly volatility, it must be sealed and stored in a cool dark place. These esters spices are rarely used alone and are generally blended with a variety of other spices for application.
(2) Non-ester spices are mainly spices including alcohols, aldehydes, volatile acids, and ketones that exclude ester spices, wherein the aldehyde, the phenol and structure having unstable double bond occupies the majority of them. They can be easily oxidized in the air and should be given full attention.
In particular, the aromatic aldehydes that can have cannizarro reaction such as anisaldehyde, vanillin, ethyl vanillin, benzaldehyde, pepper aldehyde and aldehyde having double bond nearly to the aldehyde group (α- amyl cinnamaldehyde, cinnamic aldehyde and citral) are non-unstable esters spices. They are rarely used alone except vanillin and menthol with being blended with other spices for application in most cases.
Artificial spices are flavor components that have not been identified in the natural product (no matter whether or not processed) for human consumption. Such spices have fewer varieties with all of them manufactured by chemical methods, and their chemical structures have not yet been found in nature.
Based on this, the safety of these spices has drawn a lot of attention. In China, those spices included in the GB/T14156-93 "edible spices and coding" all have undergone certain toxicological evaluation, and are considered harmless to humans (in certain doses). Among them, except individual spices undergoing adequate toxicological evaluation, they are all currently classified as temporary license. It should be noted that, with the continuous development of science and technology and human awareness, some varieties originally belonging to artificial spice varieties have also found in some natural foods, thus being classified as nature-identical flavors. For example, the artificial spice, allyl caproate, temporarily used in China is now re-classified as nature-identical spice internationally.
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- Structure:
- Chemical Name:
- Ethyl nonanoate
- CAS:
- 123-29-5
- MF:
- C11H22O2
- Structure:
- Chemical Name:
- 1,8-Cineole
- CAS:
- 470-82-6
- MF:
- C10H18O
- Structure:
- Chemical Name:
- Isobutyl formate
- CAS:
- 542-55-2
- MF:
- C5H10O2
- Structure:
- Chemical Name:
- 2-Ethylhexyl acetate
- CAS:
- 103-09-3
- MF:
- C10H20O2
- Structure:
- Chemical Name:
- Phenylacetic acid isobutyl ester
- CAS:
- 102-13-6
- MF:
- C12H16O2
- Structure:
- Chemical Name:
- 4-Methylbenzyl alcohol
- CAS:
- 589-18-4
- MF:
- C8H10O
- Structure:
- Chemical Name:
- 4-ISOPROPYLBENZYL ALCOHOL
- CAS:
- 536-60-7
- MF:
- C10H14O
- Structure:
- Chemical Name:
- 2,3-Pyrazinedicarboxylic acid
- CAS:
- 89-01-0
- MF:
- C6H4N2O4
- Structure:
- Chemical Name:
- GERANYL PROPIONATE
- CAS:
- 105-90-8
- MF:
- C13H22O2
- Structure:
- Chemical Name:
- 1-Nonanal
- CAS:
- 124-19-6
- MF:
- C9H18O
- Structure:
- Chemical Name:
- trans-2-Hexenyl acetate
- CAS:
- 2497-18-9
- MF:
- C8H14O2
- Structure:
- Chemical Name:
- Dimeric mercapto propanone
- CAS:
- 55704-78-4
- MF:
- C6H12O2S2
- Structure:
- Chemical Name:
- 3-(Methylthio)butanal
- CAS:
- 16630-52-7
- MF:
- C5H10OS
- Structure:
- Chemical Name:
- 2-Acetyl-3,5-dimethylpyrazine
- CAS:
- 54300-08-2
- MF:
- C8H10N2O
- Structure:
- Chemical Name:
- Isolongifolene
- CAS:
- 1135-66-6
- MF:
- C15H24
- Structure:
- Chemical Name:
- Cyclopentadecanone
- CAS:
- 502-72-7
- MF:
- C15H28O
- Structure:
- Chemical Name:
- 2-Furfurylthio-3-methylpyrazine
- CAS:
- 65530-53-2
- MF:
- C10H10N2OS
- Structure:
- Chemical Name:
- Isobutyl butyrate
- CAS:
- 539-90-2
- MF:
- C8H16O2
- Structure:
- Chemical Name:
- DODECYL ACETATE
- CAS:
- 112-66-3
- MF:
- C14H28O2
- Structure:
- Chemical Name:
- 2,5-Dimethylthiazole
- CAS:
- 4175-66-0
- MF:
- C5H7NS
- Structure:
- Chemical Name:
- cis-3-Hexenyl Acetate
- CAS:
- 3681-71-8
- MF:
- C8H14O2
- Structure:
- Chemical Name:
- Dimedone
- CAS:
- 126-81-8
- MF:
- C8H12O2
- Structure:
- Chemical Name:
- Methyl 2-(methylamino)benzoate
- CAS:
- 85-91-6
- MF:
- C9H11NO2
- Structure:
- Chemical Name:
- 2,3-Dichloropyrazine
- CAS:
- 4858-85-9
- MF:
- C4H2Cl2N2
- Structure:
- Chemical Name:
- Methyl butyrate
- CAS:
- 623-42-7
- MF:
- C5H10O2
- Structure:
- Chemical Name:
- Hexyl isobutyrate
- CAS:
- 2349-07-7
- MF:
- C10H20O2
- Structure:
- Chemical Name:
- PHENYLACETALDEHYDE DIMETHYL ACETAL
- CAS:
- 101-48-4
- MF:
- C10H14O2
- Structure:
- Chemical Name:
- Ethyl tiglate
- CAS:
- 5837-78-5
- MF:
- C7H12O2
- Structure:
- Chemical Name:
- Furfuryl thioacetate
- CAS:
- 13678-68-7
- MF:
- C7H8O2S
- Structure:
- Chemical Name:
- 2-Mercapto-3-butanol
- CAS:
- 37887-04-0
- MF:
- C4H10OS
- Structure:
- Chemical Name:
- Phenethyl isobutyrate
- CAS:
- 103-48-0
- MF:
- C12H16O2
- Structure:
- Chemical Name:
- Citronellyl acetate
- CAS:
- 150-84-5
- MF:
- C12H22O2
- Structure:
- Chemical Name:
- Terpinyl acetate
- CAS:
- 80-26-2
- MF:
- C12H20O2
- Structure:
- Chemical Name:
- Propyl 2-methyl-3-furyl disulfide
- CAS:
- 61197-09-9
- MF:
- C8H12OS2
- Structure:
- Chemical Name:
- TRANS-2-HEXENAL
- CAS:
- 6728-26-3
- MF:
- C6H10O
- Structure:
- Chemical Name:
- Isopentyl formate
- CAS:
- 110-45-2
- MF:
- C6H12O2
- Structure:
- Chemical Name:
- Butyl salicylate
- CAS:
- 2052-14-4
- MF:
- C11H14O3
- Structure:
- Chemical Name:
- 2-Acetyl-3-ethylpyrazine
- CAS:
- 32974-92-8
- MF:
- C8H10N2O
- Structure:
- Chemical Name:
- P-TOLYL ACETATE
- CAS:
- 140-39-6
- MF:
- C9H10O2
- Structure:
- Chemical Name:
- Methyl allyl disulfide
- CAS:
- 2179-58-0
- MF:
- C4H8S2
- Structure:
- Chemical Name:
- 2,3-HEXANEDIONE
- CAS:
- 3848-24-6
- MF:
- C6H10O2
- Structure:
- Chemical Name:
- 3-Methylindole
- CAS:
- 83-34-1
- MF:
- C9H9N
- Structure:
- Chemical Name:
- cis-3-Hexenyl tiglate
- CAS:
- 67883-79-8
- MF:
- C11H18O2
- Structure:
- Chemical Name:
- Dibenzyl disulfide
- CAS:
- 150-60-7
- MF:
- C14H14S2
- Structure:
- Chemical Name:
- 3,7-Dimethyl-2,6-octadienenitrile
- CAS:
- 5146-66-7
- MF:
- C10H15N
- Structure:
- Chemical Name:
- Diallyl trisulfide
- CAS:
- 2050-87-5
- MF:
- C6H10S3
- Structure:
- Chemical Name:
- (-)-FENCHONE
- CAS:
- 7787-20-4
- MF:
- C10H16O
- Structure:
- Chemical Name:
- 2-Methoxy-3-methylpyrazine
- CAS:
- 2847-30-5
- MF:
- C6H8N2O
- Structure:
- Chemical Name:
- Methyl 2-methoxybenzoate
- CAS:
- 606-45-1
- MF:
- C9H10O3
- Structure:
- Chemical Name:
- 4-Fluorocinnamaldehyde
- CAS:
- 24654-55-5
- MF:
- C9H7FO
- Structure:
- Chemical Name:
- Methyl Cedryl Ketone
- CAS:
- 32388-55-9
- MF:
- C17H26O
- Structure:
- Chemical Name:
- Ethyl 3-(furfurylthio)propionate
- CAS:
- 94278-27-0
- MF:
- C10H14O3S
- Structure:
- Chemical Name:
- 4-Methoxy-2,5-dimethyl-3(2H)-furanone
- CAS:
- 4077-47-8
- MF:
- C7H10O3
- Structure:
- Chemical Name:
- HEXYL FORMATE
- CAS:
- 629-33-4
- MF:
- C7H14O2
- Structure:
- Chemical Name:
- Linalyl acetate
- CAS:
- 115-95-7
- MF:
- C12H20O2
- Structure:
- Chemical Name:
- Bis(methylthio)methane
- CAS:
- 1618-26-4
- MF:
- C3H8S2
- Structure:
- Chemical Name:
- Benzyl mercaptan
- CAS:
- 100-53-8
- MF:
- C7H8S
- Structure:
- Chemical Name:
- FEMA 2296
- CAS:
- 103-61-7
- MF:
- C13H16O2
- Structure:
- Chemical Name:
- Methyl anthranilate
- CAS:
- 134-20-3
- MF:
- C8H9NO2
- Structure:
- Chemical Name:
- 5-Methyl furfural
- CAS:
- 620-02-0
- MF:
- C6H6O2
- Structure:
- Chemical Name:
- Dibutyl sulfide
- CAS:
- 544-40-1
- MF:
- C8H18S
- Structure:
- Chemical Name:
- 2-PHENYLPROPIONALDEHYDE
- CAS:
- 93-53-8
- MF:
- C9H10O
- Structure:
- Chemical Name:
- Isopentyl phenylacetate
- CAS:
- 102-19-2
- MF:
- C13H18O2
- Structure:
- Chemical Name:
- 3,4-Dimethoxycinnamic acid
- CAS:
- 2316-26-9
- MF:
- C11H12O4
- Structure:
- Chemical Name:
- Methyl cyclopentenolone
- CAS:
- 80-71-7
- MF:
- C6H8O2
- Structure:
- Chemical Name:
- 4'-Methoxyacetophenone
- CAS:
- 100-06-1
- MF:
- C9H10O2
- Structure:
- Chemical Name:
- delta-Nonalactone
- CAS:
- 3301-94-8
- MF:
- C9H16O2
- Structure:
- Chemical Name:
- BENZYL PHENYLACETATE
- CAS:
- 102-16-9
- MF:
- C15H14O2
- Structure:
- Chemical Name:
- Piperonylonitrile
- CAS:
- 4421-09-4
- MF:
- C8H5NO2
- Structure:
- Chemical Name:
- Cedrol
- CAS:
- 77-53-2
- MF:
- C15H26O
- Structure:
- Chemical Name:
- Caproic acid propyl ester
- CAS:
- 626-77-7
- MF:
- C9H18O2
- Structure:
- Chemical Name:
- Butyl isobutyrate
- CAS:
- 97-87-0
- MF:
- C8H16O2
- Structure:
- Chemical Name:
- 2-(METHYLTHIO)ETHANOL
- CAS:
- 5271-38-5
- MF:
- C3H8OS
- Structure:
- Chemical Name:
- Dodecyl aldehyde
- CAS:
- 112-54-9
- MF:
- C12H24O
- Structure:
- Chemical Name:
- 4-Methylbenzyl acetate
- CAS:
- 2216-45-7
- MF:
- C10H12O2
- Structure:
- Chemical Name:
- 3-HEPTANOL
- CAS:
- 589-82-2
- MF:
- C7H16O
- Structure:
- Chemical Name:
- Furaneol
- CAS:
- 3658-77-3
- MF:
- C6H8O3
- Structure:
- Chemical Name:
- 1,6-Hexanedithiol
- CAS:
- 1191-43-1
- MF:
- C6H14S2
- Structure:
- Chemical Name:
- Methyl propyl disulfide
- CAS:
- 2179-60-4
- MF:
- C4H10S2
- Structure:
- Chemical Name:
- ETHYL ANTHRANILATE
- CAS:
- 87-25-2
- MF:
- C9H11NO2
- Structure:
- Chemical Name:
- Acetylpyrazine
- CAS:
- 22047-25-2
- MF:
- C6H6N2O
- Structure:
- Chemical Name:
- gamma-Decalactone
- CAS:
- 706-14-9
- MF:
- C10H18O2
- Structure:
- Chemical Name:
- Hendecanoic acid
- CAS:
- 112-37-8
- MF:
- C11H22O2
- Structure:
- Chemical Name:
- Diisobutylcarbinol
- CAS:
- 108-82-7
- MF:
- C9H20O
- Structure:
- Chemical Name:
- Isobutyl isovalerate
- CAS:
- 589-59-3
- MF:
- C9H18O2
- Structure:
- Chemical Name:
- DI-N-HEXYL SULFIDE
- CAS:
- 6294-31-1
- MF:
- C12H26S
- Structure:
- Chemical Name:
- Pyrazinecarbonitrile
- CAS:
- 19847-12-2
- MF:
- C5H3N3
- Structure:
- Chemical Name:
- Methyl phenylacetate
- CAS:
- 101-41-7
- MF:
- C9H10O2
- Structure:
- Chemical Name:
- 2-(Methylthio)pyrazine
- CAS:
- 21948-70-9
- MF:
- C5H6N2S
- Structure:
- Chemical Name:
- ETHYL 3-HYDROXYHEXANOATE
- CAS:
- 2305-25-1
- MF:
- C8H16O3
- Structure:
- Chemical Name:
- Ethyl heptanoate
- CAS:
- 106-30-9
- MF:
- C9H18O2
- Structure:
- Chemical Name:
- Geranyl linalool
- CAS:
- 1113-21-9
- MF:
- C20H34O
- Structure:
- Chemical Name:
- cis-3-Hexenyl hexanoate
- CAS:
- 31501-11-8
- MF:
- C12H22O2
- Structure:
- Chemical Name:
- ISOPROPYL BUTYRATE
- CAS:
- 638-11-9
- MF:
- C7H14O2
- Structure:
- Chemical Name:
- Methyl 3-methylthiopropionate
- CAS:
- 13532-18-8
- MF:
- C5H10O2S
- Structure:
- Chemical Name:
- Dimethyl trisulfide
- CAS:
- 3658-80-8
- MF:
- C2H6S3
- Structure:
- Chemical Name:
- PHENETHYL FORMATE
- CAS:
- 104-62-1
- MF:
- C9H10O2
- Structure:
- Chemical Name:
- Ethyl 3-hydroxybutyrate
- CAS:
- 5405-41-4
- MF:
- C6H12O3
- Structure:
- Chemical Name:
- 2-PHENYLETHYL PROPIONATE
- CAS:
- 122-70-3
- MF:
- C11H14O2
- Structure:
- Chemical Name:
- 4-Methoxybenzyl alcohol
- CAS:
- 105-13-5
- MF:
- C8H10O2