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Analytical Chemistry

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Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Structure:
Chemical Name:
SESAMOLIN
CAS:
526-07-8
MF:
C20H18O7
Structure:
Chemical Name:
Polydimethylsiloxane, dihydroxy terminated
CAS:
70131-67-8
MF:
HOSi
Structure:
Chemical Name:
TRILINOLEIN
CAS:
537-40-6
MF:
C57H98O6
Structure:
Chemical Name:
2,4,5-TRIMETHYLANILINE
CAS:
137-17-7
MF:
C9H13N
Structure:
Chemical Name:
Dibromofluoromethane
CAS:
1868-53-7
MF:
CHBr2F
Chemical Name:
Sweet almond oil
CAS:
8007-69-0
Structure:
Chemical Name:
FLUMIOXAZIN
CAS:
103361-09-7
MF:
C19H15FN2O4
Structure:
Chemical Name:
3-BROMO-2-METHYLPROPIONIC ACID
CAS:
56970-78-6
MF:
C4H7BrO2
Structure:
Chemical Name:
2-(4-BIPHENYLYL)-5-PHENYL-1,3,4-OXADIAZOLE
CAS:
852-38-0
MF:
C20H14N2O
Structure:
Chemical Name:
ENDRIN
CAS:
72-20-8
MF:
C12H8Cl6O
Structure:
Chemical Name:
VIOLURIC ACID MONOHYDRATE
CAS:
26351-19-9
MF:
C4H5N3O5
Structure:
Chemical Name:
ABD-F
CAS:
91366-65-3
MF:
C6H4FN3O3S
Structure:
Chemical Name:
N-BUTYL METHANESULPHONATE
CAS:
1912-32-9
MF:
C5H12O3S
Structure:
Chemical Name:
11C,14C-EICOSADIENOIC ACID
CAS:
2091-39-6
MF:
C20H36O2
Structure:
Chemical Name:
1-(2-(TRIMETHYLSILYL)ETHOXYCARBONYLOXY)&
CAS:
78269-85-9
MF:
C10H17NO5Si
Structure:
Chemical Name:
ASTAXANTHIN
CAS:
7542-45-2
MF:
C40H52O4
Structure:
Chemical Name:
2,3-Dichloropropionic acid
CAS:
565-64-0
MF:
C3H4Cl2O2
Structure:
Chemical Name:
BENZOFENAP
CAS:
82692-44-2
MF:
C22H20Cl2N2O3
Structure:
Chemical Name:
ETIZOLAM
CAS:
40054-69-1
MF:
C17H15ClN4S
Structure:
Chemical Name:
4-Nitro-7-(1-piperazinyl)-2,1,3-benzoxadiazole
CAS:
139332-66-4
MF:
C10H11N5O3
Structure:
Chemical Name:
5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE
CAS:
25440-14-6
MF:
C44H10F20N4
Structure:
Chemical Name:
Propisochlor
CAS:
86763-47-5
MF:
C15H22ClNO2
Structure:
Chemical Name:
CORTICOSTERONE 21-ACETATE
CAS:
1173-26-8
MF:
C23H32O5
Structure:
Chemical Name:
(R)-(-)-1-Cyclohexylethylamine
CAS:
5913-13-3
MF:
C8H17N
Structure:
Chemical Name:
METHYL MELISSATE
CAS:
629-83-4
MF:
C31H62O2
Structure:
Chemical Name:
4-TRIFLUOROACETYL-3-METHYL-1-PHENYL-5-PYRAZOLONE
CAS:
1691-93-6
MF:
C12H9F3N2O2
Chemical Name:
Safflower oil
CAS:
8001-23-8
MF:
NULL
Structure:
Chemical Name:
2-(1-NAPHTHYL)-5-PHENYLOXAZOLE
CAS:
846-63-9
MF:
C19H13NO
Structure:
Chemical Name:
trans-caffeic acid
CAS:
501-16-6
MF:
C9H8O4
Structure:
Chemical Name:
DICYCLOMINE HYDROCHLORIDE
CAS:
67-92-5
MF:
C19H36ClNO2
Structure:
Chemical Name:
2,9-DIMETHYL-1,10-PHENANTHROLINE HEMIHYDRATE
CAS:
34302-69-7
MF:
C14H14N2O
Structure:
Chemical Name:
(R)-(+)-1-PHENYL-1-PROPANOL
CAS:
1565-74-8
MF:
C9H12O
Structure:
Chemical Name:
7-(2-HYDROXYETHYL)THEOPHYLLINE
CAS:
519-37-9
MF:
C9H12N4O3
Structure:
Chemical Name:
Pamabrom
CAS:
606-04-2
MF:
C11H18BrN5O3
Structure:
Chemical Name:
TERPIN MONOHYDRATE
CAS:
2451-01-6
MF:
C10H22O3
Structure:
Chemical Name:
DISPERSE ORANGE 3
CAS:
730-40-5
MF:
C12H10N4O2
Structure:
Chemical Name:
PARAOXON
CAS:
311-45-5
MF:
C10H14NO6P
Structure:
Chemical Name:
2,3,4-TRICHLOROPHENOL
CAS:
15950-66-0
MF:
C6H3Cl3O
Structure:
Chemical Name:
N-CAPROIC ACID SODIUM SALT
CAS:
10051-44-2
MF:
C6H11NaO2
Structure:
Chemical Name:
GLIOTOXIN
CAS:
67-99-2
MF:
C13H14N2O4S2
Structure:
Chemical Name:
(1R,2R,5R)-(+)-2-Hydroxy-3-pinanone
CAS:
24047-72-1
MF:
C10H16O2
Structure:
Chemical Name:
10E,12Z-octadecadienoic acid
CAS:
2420-56-6
MF:
C18H32O2
Structure:
Chemical Name:
N-(2-Ethylhexyl)-5-norbornene-2,3-dicarboximide
CAS:
113-48-4
MF:
C17H25NO2
Chemical Name:
GLOBULINS, CAT GAMMA
CAS:
9007-83-4
Structure:
Chemical Name:
N-NITROSOMORPHOLINE
CAS:
59-89-2
MF:
C4H8N2O2
Structure:
Chemical Name:
(1S)-(+)-3-Carene
CAS:
498-15-7
MF:
C10H16
Structure:
Chemical Name:
Chlortalidone
CAS:
77-36-1
MF:
C14H11ClN2O4S
Structure:
Chemical Name:
HEPTACHLOR
CAS:
76-44-8
MF:
C10H5Cl7
Structure:
Chemical Name:
Novaluron
CAS:
116714-46-6
MF:
C17H9ClF8N2O4
Structure:
Chemical Name:
AFLATOXIN G2
CAS:
7241-98-7
MF:
C17H14O7
Structure:
Chemical Name:
4-AMINO-2,6-DINITROTOLUENE
CAS:
19406-51-0
MF:
C7H7N3O4
Structure:
Chemical Name:
2-TERT-BUTYL-4-HYDROXYANISOLE
CAS:
88-32-4
MF:
C11H16O2
Structure:
Chemical Name:
4-(N,N-DIMETHYLAMINOSULFONYL)-7-FLUORO-2,1,3-BENZOXADIAZOLE
CAS:
98358-90-8
MF:
C8H8FN3O3S
Structure:
Chemical Name:
2-BUTYL-2-ETHYL-1,3-PROPANEDIOL
CAS:
115-84-4
MF:
C9H20O2
Structure:
Chemical Name:
PHTHALIC ACID MONOBENZYL ESTER
CAS:
2528-16-7
MF:
C15H12O4
Structure:
Chemical Name:
4,4'-Dihydroxytetraphenylmethane
CAS:
1844-01-5
MF:
C25H20O2
Structure:
Chemical Name:
GRAM'S IODINE
CAS:
12298-68-9
MF:
I3K
Structure:
Chemical Name:
AZINPHOS-METHYL
CAS:
86-50-0
MF:
C10H12N3O3PS2
Structure:
Chemical Name:
7H-DIBENZO[C,G]CARBAZOLE
CAS:
194-59-2
MF:
C20H13N
Structure:
Chemical Name:
AFLATOXIN B2
CAS:
7220-81-7
MF:
C17H14O6
Structure:
Chemical Name:
2-Methyl-4-nitroimidazole
CAS:
696-23-1
MF:
C4H5N3O2
Structure:
Chemical Name:
1-Isobutyl-4-piperidone
CAS:
72544-16-2
MF:
C9H17NO
Structure:
Chemical Name:
Oxethazaine
CAS:
126-27-2
MF:
C28H41N3O3
Structure:
Chemical Name:
TEOC-ONP
CAS:
80149-80-0
MF:
C12H17NO5Si
Structure:
Chemical Name:
1-(2-THIAZOLYLAZO)-2-NAPHTHOL
CAS:
1147-56-4
MF:
C13H9N3OS
Structure:
Chemical Name:
7-Amino-3-(1,2,3-triazol-4-ylthio)methyl cephalosporanic acid
CAS:
37539-03-0
MF:
C10H11N5O3S2
Structure:
Chemical Name:
METHYL RICINOLEATE
CAS:
141-24-2
MF:
C19H36O3
Structure:
Chemical Name:
FENCHOL
CAS:
1632-73-1
MF:
C10H18O
Structure:
Chemical Name:
DEOXYNIVALENOL
CAS:
51481-10-8
MF:
C15H20O6
Structure:
Chemical Name:
Nitrosobenzene
CAS:
586-96-9
MF:
C6H5NO
Structure:
Chemical Name:
3-CARBAMYL-1-METHYLPYRIDINIUM CHLORIDE
CAS:
1005-24-9
MF:
C7H9ClN2O
Structure:
Chemical Name:
Clopamide
CAS:
636-54-4
MF:
C14H20ClN3O3S
Structure:
Chemical Name:
Clobetasone butyrate
CAS:
25122-57-0
MF:
C26H32ClFO5
Structure:
Chemical Name:
2-[4-Aminosulfonyl-phenyl]-ethyl-5-methylpyrazinecarboxamide
CAS:
33288-71-0
MF:
C14H16N4O3S
Structure:
Chemical Name:
ELAIDIC ACID METHYL ESTER
CAS:
1937-62-8
MF:
C19H36O2
Structure:
Chemical Name:
N-(4-AMINOBUTYL)-2-NAPHTHALENESULFONAMIDE HYDROCHLORIDE
CAS:
89108-46-3
MF:
C14H19ClN2O2S
Structure:
Chemical Name:
INDENO(1,2,3-C,D)PYRENE
CAS:
193-39-5
MF:
C22H12
Structure:
Chemical Name:
PONCEAU 3R
CAS:
3564-09-8
MF:
C19H19N2NaO7S2
Structure:
Chemical Name:
8-METHYLNONANOIC ACID
CAS:
5963-14-4
MF:
C10H20O2
Structure:
Chemical Name:
CARAZOLOL HCL
CAS:
57775-29-8
MF:
C18H22N2O2
Chemical Name:
Somatotropin
CAS:
12629-01-5
MF:
C990H1529N263O299S7
Structure:
Chemical Name:
Prednisolone succinate
CAS:
2920-86-7
MF:
C25H32O8
Structure:
Chemical Name:
FMOC-HYDRAZIDE HCL
CAS:
35661-51-9
MF:
C15H14N2O2
Structure:
Chemical Name:
Trinexapac-ethyl
CAS:
95266-40-3
MF:
C13H16O5
Structure:
Chemical Name:
Etifenin
CAS:
63245-28-3
MF:
C16H22N2O5
Structure:
Chemical Name:
MECOPROP
CAS:
7085-19-0
MF:
C10H11ClO3
Structure:
Chemical Name:
3-Pyridyl dimethylcarbamate
CAS:
51581-32-9
MF:
C8H10N2O2
Structure:
Chemical Name:
N-(2,2,2-TRICHLOROETHOXYCARBONYLOXY)SUCCINIMIDE
CAS:
66065-85-8
MF:
C7H6Cl3NO5
Structure:
Chemical Name:
Dinitramine
CAS:
29091-05-2
MF:
C11H13F3N4O4
Structure:
Chemical Name:
Pyributicarb
CAS:
88678-67-5
MF:
C18H22N2O2S
Structure:
Chemical Name:
Amylmetacresol
CAS:
1300-94-3
MF:
C12H18O
Structure:
Chemical Name:
17-OCTADECYNOIC ACID
CAS:
34450-18-5
MF:
C18H32O2
Structure:
Chemical Name:
ARALDITE M
CAS:
3101-60-8
MF:
C13H18O2
Structure:
Chemical Name:
2-Mercaptoethanesulfonic acid
CAS:
3375-50-6
MF:
C2H6O3S2
Structure:
Chemical Name:
N-DESMETHYLCLOZAPINE
CAS:
6104-71-8
MF:
C17H17ClN4
Structure:
Chemical Name:
PENTACHLOROANISOLE
CAS:
1825-21-4
MF:
C7H3Cl5O
Chemical Name:
Soybean Flour
CAS:
68513-95-1
Structure:
Chemical Name:
2,3,4,5-TETRACHLOROPHENOL
CAS:
4901-51-3
MF:
C6H2Cl4O
Structure:
Chemical Name:
Terbacil
CAS:
5902-51-2
MF:
C9H13ClN2O2
Structure:
Chemical Name:
BROMOPRIDE
CAS:
4093-35-0
MF:
C14H22BrN3O2